首页|(NH4)2S2O8/AC电极制备及其电吸附性能

(NH4)2S2O8/AC电极制备及其电吸附性能

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为了制备电化学性能更优的活性炭电极,利用(NH4)2S2O8浸渍得到改性后的APS-AC,运用EST技术筛选石墨烯微片、导电炭黑、碳纳米管中更佳的导电剂,制备电化学性能更优的APS-AC电极;通过CV、EIS、GCD和CA等测试手段比较APS-AC电化学性能,并结合吸附行动力学分析电吸附性能和吸附规律.结果表明:导电炭黑制备的APS-AC电极性能更佳,比电容为275.208 F/g;表征发现APS-AC电极的接触角变小,亲水性提高;充放电周期大,充放电性能和电荷储存能力更好.溶液中不同阴阳离子的吸附效果不同,离子去除率为K+>Na+、Cl->SO42-,吸附过程更符合准二级吸附动力学.
Preparation and electrosorption performance of(NH4)2S2O8/AC electrode
In order to prepare activated carbon electrodes with better electrochemical performance,modified activated carbon(APS-AC)was obtained by impregnation with(NH4)2S2O8.The better conductive agents in graphene microsheets,conductive carbon black,and carbon nanotubes were screened through EST tech-nology to prepare APS-AC electrodes with better electrochemical performance.We compared the electro-chemical performance of APS-AC through testing methods such as CV,EIS,GCD,and CA,and analyzed the electro adsorption performance and adsorption law in combination with adsorption kinetics.The results showed that the APS-AC electrode prepared with conductive carbon black had better performance,with a specific capacitance of 275.208 F/g.Through characterization,it was found that the contact angle of the APS-AC electrode decreased and the hydrophilicity improved.A longer charging and discharging cycle re-sults in better charging and discharging performance and charge storage capacity.The adsorption efficiency of different anions and cations in the solution varies,with ion removal rates being K+>Na and Cl->SO4-.The adsorption process is more in line with quasi second order adsorption kinetics.

activated carbonactivated carbon modificationelectrode preparationadsorption ki-neticselectrosorption properties

裴盼盼、李海红、吴沁如

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陕西省现代建筑设计研究院,陕西西安 710021

西安工程大学环境与化学工程学院,陕西西安 710048

活性炭 活性炭改性 电极制备 吸附动力学 电吸附性能

陕西省科技厅社会发展项目榆林市科技计划

2020SF-435CXY-2020-054

2024

西安工程大学学报
西安工程大学

西安工程大学学报

CSTPCD
影响因子:0.473
ISSN:1674-649X
年,卷(期):2024.38(2)
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