首页|1,3-二甲基咪唑-2-羧酸盐辅助制备SnO2量子点及其对乙醇的气敏性

1,3-二甲基咪唑-2-羧酸盐辅助制备SnO2量子点及其对乙醇的气敏性

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为了制备气体灵敏度良好的SnO2量子点,以聚乙二醇200(PEG200)为分散剂,采用咪唑基离子液体前驱体1,3-二甲基咪唑-2-羧酸盐辅助制备粒径约为4 nm、气敏性良好的SnO2量子点.利用X射线衍射仪、高分辨率透射电镜对SnO2量子点的物相结构和微观形貌样品进行表征,通过傅里叶变换红外光谱仪、紫外-可见分光光度计和比表面积分析仪测试SnO2量子点的纯度、光学性质和比表面积,并采用气敏测试系统检测SnO2量子点对乙醇气体的灵敏度.结果显示:制备的SnO2量子点颗粒大小均匀,比表面积为123.89 m2/g,对可见光透过率达90%以上,乙醇气敏性能优良;在250 ℃,乙醇体积分数为300×10-6时,SnO2量子点的灵敏度可达195.34.
Synthesis of SnO2 quantum dots with 1,3-dimethylimidazolium-2-carboxylate as inducing agent and the gas sensitive performance to ethanol
In order to obtain SnO2 quantum dots with good gas response,the SnO2 quantum dots with diameters of about 4 nm were successfully synthesized by using 1,3-dimethyl imidazolium-2-carboxylate(1,3-diMiM-2-COO)as inducing agent and polyethylene glycol 200(PEG200)as dispersant.The struc-ture and morphology of SnO2 quantum dots were characterized by X-ray diffraction and high resolution transmission electron microscope.The purity,optical properties,and the specific surface area of SnO2 quantum dots were tested by FT-IR,UV-Vis spectrophotometer and specific surface analyzer,respective-ly.The response to ethanol gas was also tested.The results show that the prepared SnO2 quantum dots have uniform particle size,specific surface area of 123.89 m2/g,visible light transmittance of more than 90%,excellent ethanol gas sensitivity,and the sensitivity of SnO2 quantum dots can be up to 195.34 at 250 ℃ and ethanol volume fraction of 300×10-6.

SnO2 quantum dots1,3-dimethylimidazolium-2-carboxylateoptical propertiesgas sensitive performance

刘松涛、郑贤军、杨凯、孙仲明、方晨羽、侯海云

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西安工程大学材料工程学院,陕西西安 710048

西安工程大学环境与化学工程学院,陕西西安 710048

SnO2量子点 1,3-二甲基咪唑-2-羧酸盐 光学性质 气敏性能

2024

西安工程大学学报
西安工程大学

西安工程大学学报

CSTPCD
影响因子:0.473
ISSN:1674-649X
年,卷(期):2024.38(4)