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高强Cu-Ni-Al合金的力学性能及其耐腐蚀性能

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为提高Cu-10Ni合金的力学和耐腐蚀性能,利用Al代替部分Ni,采用真空感应熔炼法制备高强耐蚀Cu-Ni-Al合金.借助SEM、XRD、万能试验机、静态浸泡和电化学站等,分析在Cu-Ni合金体系中引入Al元素对合金组织形貌、力学性能和耐腐蚀性能的影响.结果表明,在Cu-Ni合金体系中引入Al元素后,合金的硬度、抗拉强度、屈服强度均有明显提升;合金的塑性虽有所降低,但其延伸率仍大于40%.在NaCl溶液中长时间浸泡会在合金表面形成Cu2O和Cu2(OH)3Cl双层膜结构,可阻碍腐蚀介质进一步腐蚀基体表面.对比其腐蚀速率并通过电化学测试进一步分析验证,腐蚀周期为72 h时,Cu-10Ni、Cu-9Ni-1Al合金的腐蚀速率分别为0.005 8 mm/a、0.006 8 mm/a;336 h时,合金腐蚀速率降低至0.003 5 mm/a、0.001 8 mm/a,证明引入Al元素的Cu-Ni-Al合金的腐蚀速率随时间的增加而降低,保护膜稳定后腐蚀速率更慢,耐腐蚀性能优于Cu-10Ni合金.
Mechanical properties and corrosion resistance of Cu-Ni-Al alloy
In order to improve the mechanical and corrosion resistance of Cu-10Ni alloy,the Cu-Ni-Al alloy with high strength and corrosion resistance was prepared by vacuum induction melt-ing.SEM,XRD,universal testing machine,static immersion and electrochemical station were used to explore the effects of Al on the microstructure,mechanical properties and corrosion resistance of Cu-Ni alloy system.The results show that the hardness,tensile strength and yield strength of alloy significantly increased after the addition of Al element.Although the plasticity of the alloy decreases,its elongation is still greater than 40%,and the plasticity is good.The double-layer film structure of Cu2O and Cu2(OH)3Cl can form on the surface of the alloy in NaCl solution,which can prevent the corrosive medium from further corroding the surface of matrix.The corro-sion rates of Cu-10Ni and Cu-9Ni-1Al alloys are 0.005 8 mm/a and 0.006 8 mm/a,respectively,when the corrosion cycle is 72 h.At 336 h,the corrosion rate of the alloys decreased to 0.003 5 mm/a and 0.001 8 mm/a,which shows that adding Al element can decrease corrosion rate to a great ex-tent.The corrosion rate of Cu-9Ni-1Al is slower after the protective film stabilization,so the cor-rosion resistance is better than that of Cu-10Ni alloy.

Cu-Ni-Al alloymechanical propertiesstatic immersioncorrosion resistance

常延丽、张高序、车超杰

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西安工程大学 材料工程学院,陕西 西安 710048

Cu-Ni-Al合金 力学性能 静态浸泡 耐腐蚀性能

2024

西安工程大学学报
西安工程大学

西安工程大学学报

CSTPCD
影响因子:0.473
ISSN:1674-649X
年,卷(期):2024.38(6)