稀土氧化镨对氧化镁陶瓷性能的影响
Effects of Praseodymium Oxide on Properties of Magnesia Ceramics
狄玉丽 1何霞 1邹阳雪 1焦钰 1王城 1黄海燕1
作者信息
- 1. 西昌学院理学院,四川 西昌 615013
- 折叠
摘要
为探究添加不同质量分数的稀土氧化镨(Pr6O11)对氧化镁(MgO)陶瓷材料烧结、硬度及抗热震性能的影响,采用MgO粉末为原料,Pr6O11作为添加剂,聚乙烯醇(PVA)为黏结剂,干压成型后常压烧结制得氧化镁陶瓷材料;其成型烧结温度为1 580℃并保温3 h,然后检测MgO陶瓷的物相、烧结性能、硬度、表面形貌及抗热震性能.结果表明:Pr6O11对MgO陶瓷材料的烧结性能(密度和收缩率)有一定增强效果但增幅不大,而对MgO的硬度和抗热震性增强效果显著;当稀土Pr6O11的添加量为8%时,MgO陶瓷的洛氏硬度和抗热震次数最高,分别为60.1 HRA和17次.
Abstract
Magnesia ceramics is made from magnesium oxide(MgO)powder as raw material,rare earth praseodymium oxide(Pr6O11)as additive,and polyvinyl alcohol(PVA)as binding agent,through dry-pressing molding and pressure-less sintering methods.We investigated the crystal phase,sintering properties,hardness,morphology and thermal shock resistance properties of MgO ceramics,which was made at the sintering temperature of 1 580℃ for 3 h.The Pr6O11 was added for investigation into the effect of different contents of RE oxides on sintering,hardness,and thermal shock resis-tance of MgO ceramics.The results showed that the Pr6O11 had certain enhancement effect on the sintering properties(density and shrinkage ratio)of MgO ceramics but not very much;however,the hardness and thermal shock resistance of MgO were significantly enhanced,and when the added Pr6O11 content was 8%,MgO ceramics enjoys the optimal hard-ness and thermal shock resistance properties,which were 60.1 HRA and 17 times,respectively.
关键词
氧化镁陶瓷/稀土氧化物/氧化镨/烧结性能/抗热震性能Key words
magnesia ceramics/rare earth oxide/praseodymium oxide/sintering properties/thermal shock resistance引用本文复制引用
基金项目
四川省粉末冶金工程技术研究中心开放基金课题项目(SC-FMYJ2021-12)
西昌学院博士科研启动项目(YBZ202143)
凉山州州科技局项目(22ZDYF0190)
凉山州州科技局项目(21ZDYF0202)
出版年
2024
NETL
NSTL
维普
万方数据