首页|异质结型KBiO3/BiOCl光催化剂制备及其可见光光催化性能

异质结型KBiO3/BiOCl光催化剂制备及其可见光光催化性能

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铋酸钾具有良好的光催化性能,但稳定性差,通过原位转化法在铋酸钾表面生成氯氧化铋构成KBiO3/BiOCl异质结光催化剂并将其用于降解结晶紫.实验结果表明,BiOCl能有效改善铋酸钾稳定性并提高其光催化性能,构成的KBiO3/BiOCl异质结光催化剂可在可见光照下90 min内实现结晶紫完全降解,活性优于KBiO3或BiOCl.KBiO3/BiOCl异质结光催化剂可见光性能提高归因于异质结结构对吸收光区的拓宽和对电子-空穴复合率的抑制,以及原位生长的BiOCl比表面积的增大.
Synthesis of heterojunctiontype KBiO3/BiOCl photocatalyst and its visible light driven photocatalytic activities
Potassium bismuthate is an excellent photocatalyst with dis-satisfactory stability.In this research,a heterojunction KBiO3/BiOCl photocatalyst is synthesized via in-situ solid-transformation method on the surface of KBiO3 and used to photo-degrade crystal violet.The results confirm that the in-situ growth of BiOCl improves the stability of KBiO3 and enhances its photocatalytic performance effectively.Crystal violet can be completely photo-decomposed in 90 minutes with KBiO3/BiOCl heterojunction under visible light irradiation,which is better than that with pure KBiO3 or BiOCl.This performance improvement should ascribe to the broadening of light absorption spectrum,suppression of photogenerated electrons and holes recombination because of the constructed KBiO3/BiOCl heterojunction structure,and the increasing of surface area due to the in-situ growth of BiOCl.

heterojunctionvisible light driven photocatalystpotassium bismuthatebismuth oxychloride

张婷婷、曾琦荟、毕娜、袁绍军、蒋炜、梁斌

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四川大学化工学院,四川省多相流传质与反应工程重点实验室,四川成都610065

异质结 可见光光催化 铋酸钾 氯氧化铋

国家自然科学基金

21476146

2016

现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2016.36(8)
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