首页|FeCo/Hβ分子筛催化N2O低温分解的性能研究

FeCo/Hβ分子筛催化N2O低温分解的性能研究

Study on performance of FeCo/Hβ molecular sieves in catalyzing N2O decomposition at low temperature

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以过渡金属、稀土金属、碱土金属、主族金属等为活性组分,REY、USY、ZSM-5、Hβ、4A、NaX、NaY以及SAPO-34 等分子筛为载体,采用等体积浸渍法制备了负载型低温脱硝催化剂.通过XRD、BET、H2-TPR等对催化剂理化性质进行表征,探究了其催化N2O直接低温分解的性能.结果表明,负载Fe-Co双组分的Hβ分子筛催化性能最佳,相应负载量分别为 12%和6%,最佳焙烧温度为430℃.Fe12 Co6/Hβ具有较高的活性、热稳定性及良好的工业应用前景.
A supported low-temperature denitration catalyst is prepared through the incipient impregnation method,with transition metals,rare earth metals,alkaline earth metals and main group metals respectively as active components,and molecular sieves such as REY,USY,ZSM-5,4A,Hβ,NaX,NaY and SAPO-34 as carriers,respectively.The physical and chemical properties of the prepared catalysts are characterized by means of XRD,BET and H2-TPR,and their catalytic performance for direct N2O decomposition at low-temperature is also explored.Results show that Hβ molecular sieves loaded with Fe-Co as active components exhibit the best catalytic performance.The corresponding loading amount of Fe and Co is 12%and 6%,respectively.The optimum calcination temperature is 430℃.Fe12 Co6/Hβ catalyst possesses high activity and thermal stability,implying a good industrial application prospect.

nitrous oxidedirect catalytic decompositionHβ molecular sievesFe-Co bi-component

艾鑫、宋永吉、李翠清、王虹、王新承

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北京石油化工学院新材料与化工学院,燃料清洁化及高效催化减排技术北京市重点实验室,北京 102617

氧化亚氮 直接催化分解 Hβ分子筛 Fe-Co双组分

北京市属高等学校优秀青年人才培育计划项目国家自然科学基金项目国家自然科学基金项目国家自然科学基金项目

BPHR202203092219080092047601221076025

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(1)
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