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吸附法处理含吡啶废水的试验研究

Experimental study on treatment of pyridine-containing wastewater by adsorption

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利用水热碳化技术制备了一种莲房基水热炭.通过产物表征、正交实验、吸附等温线、吸附动力学、再生实验等探讨了水热炭在含吡啶废水处理中的应用.结果表明,莲房水热炭具有不同尺寸的孔隙结构,其表面分布着较为丰富的含氧官能团;水热炭吸附吡啶过程中各因素影响顺序为:吡啶初始浓度>水热炭投加量>溶液pH>吸附时间;莲房水热炭对吡啶的吸附动力学符合准二级模型,在35℃与45℃时Freundlich模型可较好地描述吸附等温线规律;25℃时莲房水热炭对吡啶的最大吸附量为 31.28 mg/g;磷酸溶液对莲房水热炭的再生效果优于NaOH溶液;莲房水热炭经 6 次再生后,对吡啶仍具较好的吸附能力.
A lotus seedpod hydrochar is prepared through using hydrothermal carbonization.The potential application of hydrochar in the treatment of pyridine-containing wastewater is explored through a series of laboratory studies,including product characterization,orthogonal experiments,adsorption isotherms,adsorption kinetics and regeneration experiment.The results indicate that the lotus seedpod hydrochar has different sizes of pore structures,and distributes abundant oxygen-containing functional groups on its surface.The order of influence of the factors during the adsorption of pyridine by hydrochar is as follows:the initial concentration of pyridine>the amount of hydrochar>pH>contact time.The adsorption of pyridine on the hydrochar accords with the quasi-secondary model,and the adsorption isotherm pattern at 35℃and 45℃ can be better described by the Freundlich model.The maximum adsorption of pyridine on the prepared hydrochar is 31.28 mg·g-1 at 25℃.Regeneration of the saturated lotus seedpod hydrochar by phosphoric acid solution is better than that by NaOH solution.After six cycles of regeneration,the prepared hydrochar still has a strong adsorption capacity for pyridine.

hydrocharadsorptionpyridinekineticsregeneration

田晓春、于慧强、刘岩、孙傲、丁康乐

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长江大学化学与环境工程学院,湖北 荆州 434023

长江大学资源与环境学院,湖北 武汉 430100

水热炭 吸附 吡啶 动力学 再生

国家自然科学基金面上项目国家自然科学基金面上项目油气资源与勘探技术教育部重点实验室开放基金

4227217541472095K2018-05

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(1)
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