A systematic review is presented about the latest research progress in the utilization of MOFs-based materials as heterogeneous catalysts,supports,and precursors for selective catalytic oxidation of cyclohexane.It involves intrinsic MOFs,MOF composites,and MOF derivatives.This review emphasizes the influences of active site type,composition,and ratio,as well as the structure and environment of pores,on the conversion rate and selectivity of cyclohexane catalytic oxidation over MOFs-based materials.Additionally,the challenges faced by MOFs-based materials are identified,and their prospects for the future are proposed.
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