现代化工2024,Vol.44Issue(3) :160-167.DOI:10.16606/j.cnki.issn0253-4320.2024.03.029

CoFe-LDHs/VMT催化剂高效电解尿素性能探究

Exploration on performance of CoFe-LDHs/VMT catalyst for efficient electrolysis of urea

孙源 董方林 田维亮 胡群洋 唐风琴
现代化工2024,Vol.44Issue(3) :160-167.DOI:10.16606/j.cnki.issn0253-4320.2024.03.029

CoFe-LDHs/VMT催化剂高效电解尿素性能探究

Exploration on performance of CoFe-LDHs/VMT catalyst for efficient electrolysis of urea

孙源 1董方林 1田维亮 1胡群洋 1唐风琴1
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作者信息

  • 1. 塔里木大学化学化工学院,新疆 阿拉尔 843300
  • 折叠

摘要

尿素辅助电解水是一种节能的制氢策略,但其应用受到阳极尿素氧化反应(UOR)和阴极析氢反应(HER)动力学缓慢的限制.以水热法合成的CoFe-LDHs/VMT(VMT为蛭石简写)催化剂作为UOR的高活性催化剂,通过XRD和XPS对催化剂进行表征.结果表明,VMT与CoFe-LDHs存在相互作用;CoFe-LDHs/VMT催化剂作为HER-UOR体系中的双功能电催化剂为实现节能制氢提供了新的途径.

Abstract

Urea-assisted electrolysis water represents an energy-efficient strategy for hydrogen production.However,its potential application is hampered by the sluggish kinetics of the urea oxidation reaction(UOR)at the anode and the hydrogen evolution reaction(HER)at the cathode.In this study,CoFe-LDHs/VMT,a highly active catalyst,is synthesized via a hydrothermal method,and employed for enhancing the UOR.The characterization of the catalyst by XRD and XPS reveals the interaction between VMT and CoFe-LDHs.Experimental results demonstrate that the CoFe-LDHs/VMT catalyst exhibits excellent electrocatalytic performance in the bifunctional system of HER and UOR,providing a new pathway for energy-efficient hydrogen production.

关键词

氢气/水热/双功能/电解

Key words

hydrogen/hydrothermal method/bifunctional/electrolysis

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基金项目

中央引导地方科技发展资金(Z135050009017)

中央引导地方科技发展资金(2022ZY015)

塔里木大学创新群体项目(TDZKCQ201901)

新疆建设兵团中青年科技创新领军人才项目(2020CB019)

塔里木大学校长基金(TDZKSS202234)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量34
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