现代化工2024,Vol.44Issue(3) :188-193.DOI:10.16606/j.cnki.issn0253-4320.2024.03.033

丙基唑啉改性微晶纤维素增强增韧聚乳酸的研究

Reinforcing and toughening polylactic acid with propyloxazoline modified microcrystalline cellulose

王碟 单玉华 蔡志祥 刘玮 胡林玲 刘平
现代化工2024,Vol.44Issue(3) :188-193.DOI:10.16606/j.cnki.issn0253-4320.2024.03.033

丙基唑啉改性微晶纤维素增强增韧聚乳酸的研究

Reinforcing and toughening polylactic acid with propyloxazoline modified microcrystalline cellulose

王碟 1单玉华 1蔡志祥 1刘玮 1胡林玲 1刘平1
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作者信息

  • 1. 江苏省先进催化与绿色制造协同创新中心,常州大学石油化工学院,江苏常州 213164
  • 折叠

摘要

利用丙基唑啉(POZ)对微晶纤维素(MCC)进行化学改性得到酰胺化微晶纤维素(AD-MCC),AD-MCC与聚乳酸(PLA)通过熔融共混法制备AD-MCC/PLA复合材料.利用FT-IR、SEM、XRD、TG、万能试验机等研究了 AD-MCC的制备条件,并考察了 AD-MCC添加质量分数对AD-MCC/PLA的性能影响.结果表明,在甲醇钠催化下120℃反应8 h,可得到POZ接枝率为31.47%的AD-MCC;AD-MCC提高了 MCC与PLA的相容性,使PLA力学性能显著提高;添加2.5%AD-MCC可使PLA复合材料的拉伸强度提高26%,断裂伸长率提高61%,冲击强度提高57%.

Abstract

Microcrystalline cellulose(MCC)is chemically modified with propyloxazoline(POZ)to obtain an amidated microcrystalline cellulose(AD-MCC).AD-MCC/PLA composites are prepared through melt blending of AD-MCC and polylactic acid(PLA).The preparation conditions for AD-MCC are explored by means of Fourier transform infrared spectrometer,scanning electron microscope,X-ray powder diffraction,thermogravimetric analyzer,and universal testing machine.The effect of AD-MCC addition amount on the properties of AD-MCC/PLA is studied.It is shown by the results that AD-MCC with a POZ grafting ratio of 31.47%is obtained after the reaction has performed for 8 h at 120℃under the catalysis of NaOCH3.AD-MCC improves the compatibility between MCC and PLA,and significantly enhances the mechanical properties of PLA.Compared with pure PLA,the tensile strength,elongation at break and impact strength of AD-MCC/PLA with 2.5%(wt.)of AD-MCC are increased by 26%,61%and 57%,respectively.

关键词

聚乳酸(PLA)/丙基唑啉(POZ)/酰胺化微晶纤维素(AD-MCC)/增强/增韧

Key words

polylactic acid/propyloxazoline/amidated microcrystalline cellulose/reinforcing/toughening

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出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
被引量1
参考文献量22
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