现代化工2024,Vol.44Issue(3) :206-211,217.DOI:10.16606/j.cnki.issn0253-4320.2024.03.036

基于ITO的Co-ZnO电极的制备及对邻苯二酚的检测评价

Preparation of Co-ZnO electrode based on ITO and evaluation of its detection for catechol

马寅 杨意 吴青华 缪楚宇 武莹 李宇春
现代化工2024,Vol.44Issue(3) :206-211,217.DOI:10.16606/j.cnki.issn0253-4320.2024.03.036

基于ITO的Co-ZnO电极的制备及对邻苯二酚的检测评价

Preparation of Co-ZnO electrode based on ITO and evaluation of its detection for catechol

马寅 1杨意 1吴青华 1缪楚宇 1武莹 1李宇春1
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作者信息

  • 1. 长沙理工大学化学化工学院,湖南 长沙 410000
  • 折叠

摘要

采用分布电沉积法在ITO导电玻璃表面制备Co-ZnO电极传感器,并将其用于邻苯二酚的分析检测.利用SEM、EDS和XRD对制备的Co-ZnO电极进行表面形貌、元素组成和晶体结构分析,并利用循环伏安法和计时电流法对其进行电化学分析.结果表明,Co-ZnO电极对邻苯二酚具有非常明显的电催化活性,通过测试分析得到其线性范围为0.01~10 mmol/L、灵敏度为1 429.67 mA/(mM·cm2)、检出限为0.87 µmol/L.通过干扰试验可知,Co-ZnO电极对其有良好的选择性,且电极的重现性良好.

Abstract

A Co-ZnO electrode sensor is prepared on the surface of ITO conductive glass by a distributed electrodeposition method,and used for the analysis and detection of catechol.The surface morphology,elemental composition and crystal structure of the prepared Co-ZnO electrodes are analyzed by means of SEM,EDS and XRD.Their electrochemical property is analyzed through using cyclic voltammetry and chronoamperometry.The results show that the Co-ZnO electrode has very obvious electrocatalytic activity on catechol.The linear detection range of catechol by Co-ZnO electrode is 0.01-10 mmol·L-1,the sensitivity is 1,429.67 mA·mM-1·cm-2,and the detection limit is 0.87 µmol·L-1.It is found through interference test that Co-ZnO electrodes have good selectivity and reproducibility.

关键词

邻苯二酚/ITO导电玻璃/Co-ZnO电极/电沉积

Key words

catechol/ITO conductive glass/Co-ZnO electrode/electrodeposition

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出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量25
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