首页|铁矿增强石墨相氮化碳光催化降解四环素性能及机理研究

铁矿增强石墨相氮化碳光催化降解四环素性能及机理研究

Study on photocatalytic degradation and mechanism of tetracycline by iron ore-enhanced graphite phase carbon nitride

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为提高纯氮化碳的光催化性能,增强其在处理污水中抗生素的应用,采用水热一步合成法成功合成了 CN/FeS2、CN/Fe2O3、Fe2O3/FeS2复合材料.XRD、FT-IR分析结果表明,复合材料被成功制备.阐述了Z型异质结CN/FeS2中CN和FeS2之间的电子传输方式.ESR测试结果表明,超氧自由基为催化过程中的主要活性物种,其中CN/FeS2降解四环素效率高达97%,经过6次降解循环后效率降低11%.该研究为光催化合成、设计和净化污染物开辟了新途径.
In order to improve the photocatalytic performance of pure carbon nitride and enhance its application in wastewater treatment antibiotics,CN/FeS2,CN/Fe2O3,and Fe2O3/FeS2 composites are successfully synthesized via hydrothermal one-step synthesis method.The results by XRD and FT-IR analysis show that the composites are successfully prepared,a Z-type heterojunction CN/FeS2 is suggested,and the electron transport mode between CN and FeS2 is described.ESR test show that superoxide free radicals represent the main active species in the catalytic process,and the efficiency of CN/FeS2 in degrading tetracycline is as high as 97%.After six degradation cycles,the efficiency declines by 11%.This study opens up a new way for photocatalytic synthesis,as well as the design and purification of pollutants.

carbon nitrideiron sesquioxidepyritephotocatalysistetracycline

周彤、董国辉

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陕西科技大学环境科学与工程学院,陕西 西安 843300

氮化碳 三氧化二铁 黄铁矿 光催化 四环素

国家自然科学基金国家自然科学基金

2187610421603109

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(4)
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