首页|氢氧化镁的表面改性及其在硅橡胶中的阻燃性能研究

氢氧化镁的表面改性及其在硅橡胶中的阻燃性能研究

Surface modification of magnesium hydroxide and its flame-retardant performance for silicone rubber

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分别采用乙烯基三乙氧基硅烷(VTES)、乙基三乙氧基硅烷(ETES)以及3-(氨基丙基)三乙氧基硅烷(APTES)对氢氧化镁(MH)进行表面改性,研究了改性工艺对改性MH粒子表面特性的影响.结果表明,确定的最佳改性条件为:改性剂为VTES、改性剂质量分数为8%、反应温度为80℃、搅拌转速为500 r/min、反应时间为2.0 h.将改性MH共混入硅橡胶,当VTES-MH质量分数为50%时,与未添加MH的硅橡胶相比,VTES-MH/硅橡胶复合材料的拉伸强度和断裂伸长率仅分别降低了 5%和11%,具有良好的力学性能;极限氧指数为40.2%,具有优良的阻燃性能.
The surface of magnesium hydroxide(MH)is modified by using vinyltriethoxysilane(VTES),ethyltriethoxy silane(ETES),and(3-aminopropyl)triethoxysilane(APTES),respectively.The influence of the modification process on the surface properties of the modified MH particles is investigated.The optimal modification conditions are determined through the experimental study as follows:VTES is used as the modifier with a mass fraction of 8%,the reaction temperature is 80℃,the stirring speed is 500 r-min-1,and the reaction has performed for 2.0 hours.The modified MH is blended into silicone rubber.Compared to silicone rubber without MH,the tensile strength and elongation at break of the silicone rubber containing 50%of VTES-MH decrease by 5%and 11%,respectively.The VTES-MH/silicone rubber composite material with such a composition exhibits good mechanical properties,delivers a limiting oxygen index of 40.2%and shows excellent flame retardant performance.

magnesium hydroxideflame retardantmodificationsilicone rubber

马树刚、万子岸、刘星池、王世荣、李祥高、侯经纬

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中国石油天然气股份有限公司石油化工研究院,北京 102206

天津大学化工学院,天津 300372

天津化学化工协同创新中心,天津 300372

氢氧化镁 阻燃剂 改性 硅橡胶

国家高技术研究发展计划(863计划)

2013AA032003

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(4)
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