首页|三维Ni3S2@NiCo-LDH纳米复合材料合成及其电氧化尿素制氢性能研究

三维Ni3S2@NiCo-LDH纳米复合材料合成及其电氧化尿素制氢性能研究

Synthesis of three-dimensional Ni3S2@NiCo-LDH nanocomposite and study on its properties in hydrogen production from electro-oxidation of urea

扫码查看
为设计高效、廉价和耐用的催化裂解水制氢电催化剂,合成了Ni3S2纳米线@NiCo-LDH纳米复合材料(Ni3S2@NiCo-LDH).结果表明,该复合材料具有大量的活性位点,表现出很好的电催化制氢性能.在含有尿素的KOH电解液中,Ni3S2@NiCo-LDH电极材料仅需1.373 V就能达到10 mA/cm2的电流密度.在双电极体系Ni3S2@NiCo-LDH//Pt中,电流密度为10 mA/cm2时电压仅为1.463 V.因此,Ni3S2@NiCo-LDH纳米复合材料是一种优良的新型催化水解产氢电催化剂.
Aiming to design efficient,inexpensive,and durable electrocatalyst for hydrogen production via catalytic cracking of water,Ni3S2 nanowire@NiCo-LDH nanocomposite(Ni3S2@NiCo-LDH)is synthesized.The results show that the prepared composite has a large number of active sites and exhibits excellent electrocatalytic hydrogen production performance.Ni3S2@NiCo-LDH electrode material achieves a current density of 10 mA·cm-2 at only 1.373 V in a KOH electrolyte containing urea.In Ni3S2@NiCo-LDH//Pt,a two-electrode system,the voltage is only 1.463 V at a current density of 10 mA·cm-2.It is verified that Ni3S2@NiCo-LDH nanocomposite is an excellent new catalytic hydrolysis hydrogen production electrocatalyst.

nanomaterialscompositecatalysishydrogen productionurea oxidation

王志豪、范金成、崔柯昕、肖国才、高善强、黄婷、谭子聪

展开 >

长沙理工大学材料科学与工程学院,湖南长沙 410000

纳米材料 复合材料 催化剂 制氢 尿素氧化

湖南省自然科学基金

2021JJ30708

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(4)
  • 54