现代化工2024,Vol.44Issue(6) :89-93.DOI:10.16606/j.cnki.issn0253-4320.2024.06.019

污泥腐殖酸基电极碳材料的制备及其电化学性能研究

Synthesis of sludge humic acid-based carbon material for electrode and study on its electrochemical properties

郭穆骞 李颖 袁喆 贾潇田 张星楠
现代化工2024,Vol.44Issue(6) :89-93.DOI:10.16606/j.cnki.issn0253-4320.2024.06.019

污泥腐殖酸基电极碳材料的制备及其电化学性能研究

Synthesis of sludge humic acid-based carbon material for electrode and study on its electrochemical properties

郭穆骞 1李颖 1袁喆 1贾潇田 1张星楠1
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作者信息

  • 1. 中北大学环境与安全工程学院,山西 太原 030051
  • 折叠

摘要

以污泥源腐殖酸为前驱物,通过改变纯化条件和活化温度制备出不同的电极材料.利用BET、XRD、Raman表征分析电极材料的结构特征.通过搭建三电极体系并利用CV、EIS、GCD和循环性能测试研究其电化学性能.结果表明,腐殖酸纯化后,再经KOH于700℃活化,所制电极材料表现出较高的比电容(275.3 F/g),其在1 A/g的电流密度下进行1 000次循环后仍保留95.57%以上的比电容,循环稳定性较好.

Abstract

Taking sludge-sourced humic acid as precursor,different electrode materials are prepared through changing purification condition and activation temperature,and their structure is characterized by means of BET,XRD,Raman and XPS.Additionally,the electrochemical properties of the prepared materials are measured by using CV,EIS,GCD and cyclic performance tests through establishing a three-electrode system.Results show that the electrode materials prepared exhibit a high specific capacitance of 275.3 F·g-1 after they are purified by humic acid and then activated by KOH at 700℃.Meanwhile,the electrode materials still maintain 95.57%of their specific capacitance after they has been recycled for 1 000 times at a current of 1 A·g-1,showing a good cycle stability.

关键词

污泥/腐殖酸/电极材料/电化学性能

Key words

sludge/humic acid/electrode material/electrochemical performance

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基金项目

山西省自然科学基金面上项目(20210302123071)

国家重点研发计划(2018YFC1801104)

国家重点研发计划(2018YFC1801105)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量27
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