现代化工2024,Vol.44Issue(6) :107-112.DOI:10.16606/j.cnki.issn0253-4320.2024.06.022

氮锰共掺生物炭活化过硫酸盐降解安塞蜜的研究

Nitrogen-manganese co-doped biochar activated persulfate for degrading acesulfame-K

杨威 王国相 冯清茂 陈俊楠 余晨晖
现代化工2024,Vol.44Issue(6) :107-112.DOI:10.16606/j.cnki.issn0253-4320.2024.06.022

氮锰共掺生物炭活化过硫酸盐降解安塞蜜的研究

Nitrogen-manganese co-doped biochar activated persulfate for degrading acesulfame-K

杨威 1王国相 1冯清茂 2陈俊楠 1余晨晖1
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作者信息

  • 1. 哈尔滨商业大学食品工程学院,黑龙江哈尔滨 150028
  • 2. 黑龙江大学化学化工与材料学院功能无机材料化学教育部重点实验室,黑龙江哈尔滨 150080
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摘要

考察了高温热解法制备的氮锰共掺生物炭协同过硫酸盐降解水中新兴污染物安塞蜜的效能与机制.表征结果表明,氮锰共掺生物炭具有良好的比表面积与孔径结构.实验结果表明,氮锰共掺生物炭协同过硫酸盐能够显著提升水中安塞蜜的降解率,表现出更高的降解效能;在催化剂投加质量浓度为2.5 g/L、过硫酸盐浓度为8 mmol/L及不改变初始溶液pH的条件下,120 min时对安塞蜜的去除率高达94.17%.降解反应以硫酸根自由基为主导自由基.氮锰共掺生物炭具有良好的活化性能和回收利用率.

Abstract

The efficacy and mechanism of nitrogen/manganese co-doped biochar,which is prepared via high-temperature pyrolysis,together with persulfate for the synergistic degradation of acesulfame-K,an emerging pollutant,in water are investigated.Characterization results show that the nitrogen-manganese co-doped biochar has good specific surface area and pore size structure.It is shown by experimental results that the nitrogen-manganese co-doped biochar together with persulfate can significantly enhance the degradation rate of acesulfame-K in water.The removal rate of acesulfame-K reaches as high as 94.17%in 120 min under the conditions that the dosage of catalyst is 2.5 g·L-1,the concentration of persulfate is 8 mmol·L-1 and the pH of the initial solution remains unchanged.The degradation reaction is characterized by taking sulfate radicals as the dominant radicals.Nitrogen-manganese co-doped biochar has good activation performance and recycling rate.

关键词

生物炭/过硫酸盐/活化/硫酸根/降解/安塞蜜

Key words

biochar/persulfate/activation/sulfate/degradation/acesulfame-K

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基金项目

国家自然科学基金面上项目(81273079)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量17
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