现代化工2024,Vol.44Issue(6) :118-122,128.DOI:10.16606/j.cnki.issn0253-4320.2024.06.024

MnFe2O4/AC活化过硫酸盐去除水中双酚A的性能研究

Study on removal of bisphenol A from water by MnFe2O4/AC activated persulfate

张文强 杨长河 邵辉良 操泽贤 江远飞
现代化工2024,Vol.44Issue(6) :118-122,128.DOI:10.16606/j.cnki.issn0253-4320.2024.06.024

MnFe2O4/AC活化过硫酸盐去除水中双酚A的性能研究

Study on removal of bisphenol A from water by MnFe2O4/AC activated persulfate

张文强 1杨长河 1邵辉良 1操泽贤 1江远飞1
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作者信息

  • 1. 南昌大学资源与环境学院,江西南昌 330031
  • 折叠

摘要

采用水热合成法制备了活性炭负载的铁锰氧化物(MnFe2O4/AC),并将其用于活化过二硫酸盐(PDS)对水中双酚A(BPA)进行降解.研究了 PDS浓度、MnFe2O4/AC投加量以及初始pH对BPA降解效率的影响,结果表明,在一定范围内,BPA的降解率随PDS浓度以及MnFe2O4/AC投加量的增大而升高,在PDS浓度为1.0 mmol/L、MnFe2O4/AC投加质量浓度为5 mg/L时BPA降解效率趋于稳定;初始pH为5时,BPA降解率最高,且在pH为3~9内BPA均能有效被去除.无机阴离子实验表明,CO32-对该体系降解BPA的抑制作用较为明显,而Cl-和SO42-造成的影响较小.自由基淬灭实验得知,·SO4-和·OH都是体系内发挥作用的活性物质,其中·SO4-是主要活性物质,证明了 MnFe2O4/AC活化PDS降解BPA的有效性.

Abstract

Activated carbon supported iron manganese oxide(MnFe2O4/AC)is prepared through hydrothermal synthesis method,and used to activate perdisulfate(PDS)to efficiently degrade bisphenol A(BPA)in water.The influences of PDS concentration,MnFe2O4/AC dosage and initial pH on the degradation efficiency of BPA are studied.It is shown by the results that in a certain range,the degradation rate of BPA increases with the increases of PDS concentration and MnFe2O4/AC dosage.BPA degradation rate tends to be stable when PDS concentration is 1.0 mM and MnFe2O4/AC dosage is 5 mg·L-1.BPA degradation rate reaches the highest when the initial pH value is 5.In addition,BPA can be effectively removed in pH values of 3-9.It is indicated by inorganic anion experiment that CO32-significantly inhibits the degradation of BPA in this system,while Cl-and SO42-have little effect.According to the free radical quenching experiment,·SO4-and OH are both active substances that play a role in this system,of which SO4 is the main active substance.This study demonstrates the effectiveness of MnFe2O4/AC activated PDS in degrading BPA.

关键词

水热合成法/过二硫酸盐/双酚A/活化

Key words

hydrothermal synthesis/perdisulfate/bisphenol A/activation

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基金项目

江西省科技厅自然科学研究青年项目(2007gZC0075)

江西省教育厅科学技术研究项目([2007]51)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量23
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