现代化工2024,Vol.44Issue(6) :140-145.DOI:10.16606/j.cnki.issn0253-4320.2024.06.028

负载型ZnO/CuS光催化剂的制备及光催化性能研究

Preparation of supported ZnO/CuS photocatalyst and study on its photocatalytic performance

方华扬 李泉 官继伦 李雯静 唐宁岳 程芳超
现代化工2024,Vol.44Issue(6) :140-145.DOI:10.16606/j.cnki.issn0253-4320.2024.06.028

负载型ZnO/CuS光催化剂的制备及光催化性能研究

Preparation of supported ZnO/CuS photocatalyst and study on its photocatalytic performance

方华扬 1李泉 2官继伦 1李雯静 1唐宁岳 1程芳超1
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作者信息

  • 1. 广西大学资源环境与材料学院,广西南宁 530004
  • 2. 广西壮族自治区分析测试研究中心,广西南宁 530022
  • 折叠

摘要

采用连续离子层吸附反应法制备ZnO/CuS异质结光催化剂,通过与木质纤维素网络(CN)偶联成功制得负载型ZnO/CuS@CN催化剂.利用X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、扫描电子显微镜(SEM)、红外光谱(FT-IR)和电化学阻抗谱(EIS)对催化剂的元素组成、微观形貌和电学性能进行表征.通过罗丹明B(RhB)评估催化剂降解有机污染物的性能.结果表明,在模拟太阳光照射60 min后,ZnO/CuS@CN对50 mg/L RhB的降解率达到84.1%.自由基捕获实验表明,·O2-是主要活性物质.ZnO/CuS@CN对多种有机污染物均有良好的降解效果.

Abstract

ZnO/CuS heterojunction photocatalysts are prepared via the successive ionic layer adsorption reaction method,and the supported ZnO/CuS@CN catalysts are successfully prepared through coupling ZnO/CuS with cellulose network(CN).The elemental composition,micro-morphology and electrical properties of the catalysts are characterized by means of X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),scanning electron microscopy(SEM),infrared spectroscopy(FT-IR)and electrochemical impedance spectroscopy(EIS).The performance of the catalysts for the degradation of organic pollutants is evaluated by taking rhodamine B as the target.Results show that the degradation rate of 50 mg·L-1 rhodamine B by ZnO/CuS@CN reaches 84.1%after having been irradiated by simulated solar for 60 minutes.Free radical trapping experiments show that·O2 is the main active matter.ZnO/CuS@CN shows good degradation effects on a variety of organic pollutants.

关键词

氧化锌/硫化铜/异质结/负载型催化剂/光催化

Key words

ZnO/CuS/heterojunction/supported catalyst/photocatalysis

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基金项目

广西自然科学基金面上项目(2020GXNSFAA297028)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量25
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