现代化工2024,Vol.44Issue(6) :185-190.DOI:10.16606/j.cnki.issn0253-4320.2024.06.036

CeO2-CoOx/BiVO4的制备及其对有机工业废水的光催化降解研究

Preparation of CeO2-CoOx/BiVO4 and its application in photocatalytic degradation of organic industrial wastewater

孙心 段淑茹 朱开金 朱鹏宇 龙浩鹏
现代化工2024,Vol.44Issue(6) :185-190.DOI:10.16606/j.cnki.issn0253-4320.2024.06.036

CeO2-CoOx/BiVO4的制备及其对有机工业废水的光催化降解研究

Preparation of CeO2-CoOx/BiVO4 and its application in photocatalytic degradation of organic industrial wastewater

孙心 1段淑茹 1朱开金 2朱鹏宇 3龙浩鹏2
扫码查看

作者信息

  • 1. 中北大学环境与安全工程学院,山西 太原 030051;太原工业学院材料工程系,山西 太原 030008
  • 2. 太原工业学院材料工程系,山西 太原 030008
  • 3. 南京理工大学环境与生物工程学院,江苏南京 210094
  • 折叠

摘要

通过浸渍和煅烧制备了新型光催化剂BiVO4、CoOx/BiVO4与CeO2-CoOx/BiVO4,并通过XRD、SEM、TEM和XPS等手段对催化剂进行表征与分析,探讨了催化剂在不同条件下对有机工业废水的光催化性能.结果表明,CeO2-CoOx/BiVO4复合型光催化剂的降解效果最好,处理废水2 h后COD降解效率达到61%,说明掺杂负载可以有效提高催化性能;最佳光照时间为120 min,最佳投药量为1.0 g/L,且具有良好的稳定性.

Abstract

Novel photocatalysts including BiVO4,CoOx/BiVO4 and CeO2-CoOx/BiVO4 are synthesized through impregnation and calcination,and characterized by means of XRD,SEM,TEM,and XPS.Their catalytic performance for industrial wastewater under different conditions is analyzed.The results show that CeO2-CoOx/BiVO4 composite photocatalyst delivers the best degradation effect,over which the COD degradation efficiency of wastewater reaches 61%after 2 hours of treatment,indicating that doping loading can effectively improve catalytic performance.The optimal illumination time and dosage quality are 120 minutes and 1.0 g/L,respectively,and the photocatalyst has good stability.

关键词

BiVO4/光催化/可见光/工业废水/降解

Key words

BiVO4/photocatalysis/visible light/industrial wastewater/degradation

引用本文复制引用

基金项目

山西省专利转化专项(202306010)

大同市重点研发计划(2023002)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
被引量1
参考文献量24
段落导航相关论文