首页|碱水热法制备Ti3C2-Ag3PO4光催化剂及其光催化性能研究

碱水热法制备Ti3C2-Ag3PO4光催化剂及其光催化性能研究

Preparation of Ti3C2-Ag3PO4 photocatalyst via alkali hydrothermal method and evaluation of its photocatalytic performance

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通过碱水热反应合成了Ti3C2,并以其为载体制备了不同负载量的Ti3C2-Ag3PO4 光催化剂.利用FT-IR、XRD、SEM、XPS等对光催化剂进行表征.结果表明,在 240℃水热条件下,碱刻蚀法制备的Ti3C2 为刻蚀程度较低的片层结构,同时材料中有微量的TiO2 存在,同时Ag3PO4 以立方相的形式负载到Ti3C2 载体表面.随着Ag3PO4 负载量的增加,Ti3C2-Ag3PO4的光催化活性逐渐增大,在催化剂质量为0.01 g、反应时间为 60 min时,Ti3C2-Ag3PO4-85%对亚甲基蓝的降解率达到 95%.Ti3C2 与Ag3PO4 异质结的存在使其具有较强的电荷分离能力和优异的光催化性能.
Ti3C2 is synthesized through alkaline hydrothermal reaction,and used as support to prepare Ti3C2-Ag3PO4 photocatalysts with different loading amount.The photocatalysts are characterized by means of FT-IR,XRD,SEM and XPS.It is indicated that Ti3C2 prepared through alkali etching method at 240℃ hydrothermal condition presents a layer structure with low etching degree.In addition,there are trace TiO2 in Ti3C2 material,and Ag3PO4 has been supported on the surface of Ti3C2 support.The photocatalytic activity of Ti3C2-Ag3PO4 increases with the higher Ag3PO4 loading amount.The degradation rate of methylene blue by Ti3C2-Ag3PO4-85%can reach 95%when the usage of the catalyst is 0.01 g and the reaction performs 60 min.The presence of heterojunction between Ti3C2 and Ag3PO4 makes the catalyst have strong charge separation ability and excellent photocatalytic performance.

alkaline hydrothermal methodTi3C2-Ag3PO4photocatalysis

徐竞帆、周绿山、沈琪、熊信洁、刘丹、李颖、张玉、唐佳文

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四川文理学院化学化工学院,四川 达州 635000

碱水热法 Ti3C2-Ag3PO4 光催化

四川省科技厅项目绿色催化四川省高校重点实验室项目四川省大学生创新创业训练项目

2022YFG0277LZJ2202S202310644044

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(7)