首页|负载缓蚀剂埃洛石纳米管/含硅聚氨酯复合涂层的防腐性能研究

负载缓蚀剂埃洛石纳米管/含硅聚氨酯复合涂层的防腐性能研究

Research on anti-corrosion performance of elonite nanotubes/silicon-containing polyurethane composite coating

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利用二价铜离子将缓蚀剂 8-羟基喹啉封装在埃洛石纳米管内,将其加入含硅聚氨酯涂层(PU)中制备复合防腐涂层并涂覆在Q235 碳钢表面.利用傅里叶变换红外光谱、热重分析和透射电镜对封装缓蚀剂的埃洛石纳米管(HNTs/8-HQ/Cu2+)形貌和结构进行表征.在 3.5%NaCl溶液中,通过电化学阻抗谱和Tafel极化曲线表征质量分数分别为 0%、0.5%、1%、1.5%、2%和 2.5%HNTs/8-HQ/Cu2+的负载缓蚀剂埃洛石纳米管/含硅聚氨酯复合涂层(PU/HNTs)的耐腐蚀性.结果表明,PU/HNTs涂层相对PU涂层的耐腐蚀性能有显著提升,其中含PU/1.5%HNTs涂层的阻抗值达到 8.0×105 Ω·cm2,腐蚀电流密度降至(0.117±0.007)μA/cm2,缓蚀效率达到 99.22%,浸泡 30d后涂层的阻抗值依然达到9×104 Ω·cm2.
8-Hydroxyquinoline,a corrosion inhibitor,is encapsulated in elonite nanotubes by divalent copper ions,forming HNTs/8-HQ/Cu2+which is added into a silicon-containing polyurethane coating(PU)to prepare a composite anti-corrosion coating that is coated on the surface of Q235 carbon steel.The morphology and structure of HNTs/8-HQ/Cu2+are characterized through using Fourier transform infrared spectroscopy,thermogravimetric analysis,and transmission electron microscopy.In a 3.5%NaCl solution,the corrosion resistance of PU/HNTs containing 0%,0.5%,1%,1.5%,2%,and 2.5%of HNTs/8-HQ/Cu2+is characterized by means of electrochemical impedance spectroscopy and Tafel polarization curves.Characterization results show that PU/HNTs coating has a significantly higher corrosion resistance than PU coating,of which PU/1.5%HNTs coating shows an impedance value of 8.0×105 Ω·cm2,a corrosion current density of 0.117±0.007 μA·cm-2,and a corrosion inhibition efficiency of 99.22%.The impedance value of the coating still reaches 9×104 Ω·cm2 after 30 days of immersion.

anti-corrosionelonitecorrosion inhibitorsilicone-containing polyurethanecomposite coating

刘成、雷永林、朱雪梅、罗茜、梁瑶

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西南科技大学材料与化学学院,四川 绵阳 621010

防腐 埃洛石 缓蚀剂 含硅聚氨酯 复合涂层

玄武岩纤维及复合材料四川省重点实验室开放课题西南科技大学博士基金

XXKFJJ202304zx7114

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(7)