现代化工2024,Vol.44Issue(8) :110-114,120.DOI:10.16606/j.cnki.issn0253-4320.2024.08.021

花生壳基硬碳孔结构调控及储钠性能研究

Study on regulation of pore structure and sodium storage performance of peanut shell-based hard carbon

左宇程 吉闫 张京涛 邹飞杨 葛志清 陈召勇
现代化工2024,Vol.44Issue(8) :110-114,120.DOI:10.16606/j.cnki.issn0253-4320.2024.08.021

花生壳基硬碳孔结构调控及储钠性能研究

Study on regulation of pore structure and sodium storage performance of peanut shell-based hard carbon

左宇程 1吉闫 1张京涛 1邹飞杨 1葛志清 1陈召勇1
扫码查看

作者信息

  • 1. 长沙理工大学材料科学与工程学院,湖南 长沙 410114
  • 折叠

摘要

以花生壳为原料,采用固相熔融扩散碳化法调控花生壳基衍生硬碳的孔结构制得改性的花生壳衍生硬碳负极材料;通过扫描电镜(SEM)、X射线衍射(XRD)、全自动比表面及孔隙度分析仪对其进行表征分析,并对组装的钠离子半电池进行恒电流电化学充放电测试、循环伏安测试(CV)以及电化学阻抗测试.结果表明,在30 mA/g的电流密度下,材料的可逆容量达到350 mAh/g,在300 mA/g的电流密度下仍能稳定保持335 mAh/g的可逆容量,并且能在高倍率充放电下具有优异的倍率性能.

Abstract

Using peanut shell as raw material,the modified peanut shell based hard carbon anode material is prepared through using solid phase melting diffusion carbonization method to regulate the pore structure of peanut shell based hard carbon.It is characterized by means of scanning electron microscopy(SEM),X-ray diffraction(XRD)and automatic specific surface and porosity analyzer.Constant current electrochemical charge-discharge test,cyclic voltammetry test(CV)and electrochemical impedance test are carried out on the assembled sodium ion half battery.Results show that the reversible capacity of the material can reach 350 mAh·g-1 at a current density of 30 mA·g-1,and maintain at 335 mAh·g-1 stably at a current density of 300 mA·g-1.The material can have excellent magnification-rate performance at higher rate charge and discharge.

关键词

硬碳/钠离子电池/负极材料/电化学性能/孔结构

Key words

hard carbon/sodium ion battery/negative electrode material/electrochemical performance/pore structure

引用本文复制引用

基金项目

国家自然科学基金面上项目(51874048)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
段落导航相关论文