现代化工2024,Vol.44Issue(10) :132-136,143.DOI:10.16606/j.cnki.issn0253-4320.2024.10.025

金属有机骨架逐层生长法制备PET@CuBTC分级多孔纳米纤维的研究

Preparation of PET@CuBTC hierarchical porous nanofibers by layer-by-layer strategy of metal-organic frameworks

田鹏 李翔 赵伟 张鑫 克力木·吐鲁干
现代化工2024,Vol.44Issue(10) :132-136,143.DOI:10.16606/j.cnki.issn0253-4320.2024.10.025

金属有机骨架逐层生长法制备PET@CuBTC分级多孔纳米纤维的研究

Preparation of PET@CuBTC hierarchical porous nanofibers by layer-by-layer strategy of metal-organic frameworks

田鹏 1李翔 1赵伟 1张鑫 1克力木·吐鲁干1
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作者信息

  • 1. 新疆大学智能制造现代产业学院先进制膜技术实验室,新疆乌鲁木齐 840046
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摘要

以水相合成CuBTC的方法为基础,通过简单、低成本的逐层生长法制备PET(聚对苯二甲酸乙二醇酯)@CuBTC复合纤维膜.采用静电纺丝和后处理两步成功控制PET纤维的表面形貌,通过调节生长周期控制CuBTC生长尺寸形貌,制备了纤维直径均匀、比表面积高、骨架晶体层致密牢固且尺寸适中的PET@CuBTC复合纤维膜.结果表明,该方案有效解决了粉末形态MOF应用受限的问题,并证明其在高效过滤及抑菌方面具有潜在应用价值.

Abstract

Polyethylene terephthalate(PET)@CuBTC composite fiber membranes are prepared through a simple,low-cost layer-by-layer growth method based on CuBTC,which is made via aqueous phase synthesis method.Surface morphology of PET fibers produced is successfully controlled through two steps of electrospinning and post-treatment.The growth size and morphology of CuBTC is controlled through adjusting the growth cycle,and PET@CuBTC composite fiber membranes with uniform fiber diameter,high specific surface area,and dense,firm and moderate size of backbone crystal layer are prepared.Results show that this scheme effectively solves the problem that the powder form of MOF limits its application,and demonstrates the potential application value of PET@CuBTC composite fiber membranes in high efficiency filtration and bacterial inhibition.

关键词

静电纺丝/多孔结构/原位生长/CuBTC/聚对苯二甲酸乙二醇酯(PET)

Key words

electrospinning/porous structure/in situ growth/CuBTC/polyethylene terephthalate

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基金项目

新疆维吾尔自治区自然科学基金(202107120010)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量20
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