首页|CdS/SnO2复合材料的制备及其光催化还原Cr(Ⅵ)的性能研究

CdS/SnO2复合材料的制备及其光催化还原Cr(Ⅵ)的性能研究

Preparation of CdS/SnO2 composite and study on its photocatalytic performance for Cr(Ⅵ)reduction

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采用原位沉积法制备了一系列CdS/SnO2复合光催化材料,通过XRD、UV-Vis、XPS、SEM、TEM和I-t曲线对其结构和性能进行表征分析,并将其用于光催化还原Cr(Ⅵ)的研究.结果表明,CdS与SnO2复合增强了单一半导体材料的可见光吸收能力及光催化活性;当m(CdS)︰m(SnO2)为0.7时,CdS/SnO2表现出最佳的光催化活性,光照10 min后光催化还原Cr(Ⅵ)接近100%;0.7CdS/SnO2光催化剂循环使用5次后,其还原率仍为99%.将CdS与SnO2复合增强了单一半导体材料的抗光腐蚀能力,从而提高了其稳定性.
A series of CdS/SnO2 composite samples are prepared via in-situ deposition method,and characterized by using XRD,UV-Vis,XPS,SEM,TEM,and I-t curve.Subsequently,the prepared CdS/SnO2 composite is employed for the photocatalytic reduction of Cr(Ⅵ).Results show that compared to individual semiconductor material,the compounding between SnO2 and CdS enhances visible light absorption capacity and improves photocatalytic activity.CdS/SnO2 composite with a CdS/SnO2 mass ratio of 0.7 exhibits the optimal photocatalytic performance,over which the reduction rate of Cr(Ⅵ)approaches 100%within 10 min of illumination.Furthermore,the reduction rate of Cr(Ⅵ)over 0.7CdS/SnO2 photocatalyst remains at 99%even after the catalyst has undergone five cycles of use.Importantly,this synergistic combination also imparts superior corrosion resistance to these single semiconductor materials while simultaneously enhancing their stability.

CdSSnO2compositephotocatalysisCr(Ⅵ)

潘会、王瑞琼、杨子轩、朱雨璐、甄盈、徐宁宁

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湖北第二师范学院化学与生命科学学院,植物抗癌活性物质提纯与应用湖北省重点实验室,湖北武汉 430074

CdS SnO2 复合材料 光催化 Cr(Ⅵ)

湖北省教育厅指导性项目湖北第二师范学院人才启动基金

B2022210ESRC20220036

2024

现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2024.44(10)
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