现代化工2024,Vol.44Issue(10) :180-185.DOI:10.16606/j.cnki.issn0253-4320.2024.10.033

CoPC/g-C3N4的制备及其光催化降解苯酚性能研究

Preparation of CoPC/g-C3N4 and study on its performance in photocatalytic degradation of phenol

贾建岗 何淑媛
现代化工2024,Vol.44Issue(10) :180-185.DOI:10.16606/j.cnki.issn0253-4320.2024.10.033

CoPC/g-C3N4的制备及其光催化降解苯酚性能研究

Preparation of CoPC/g-C3N4 and study on its performance in photocatalytic degradation of phenol

贾建岗 1何淑媛2
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作者信息

  • 1. 山西众环创新科技有限公司,山西 太原 030024
  • 2. 中北大学化学与化工学院,山西太原 030051
  • 折叠

摘要

采用水热法制备CoPC/g-C3N4复合催化剂,并研究其光催化降解苯酚的性能.通过FT-IR、SEM、XRD、ICP、XPS以及电化学测试技术分析催化剂结构和性能关系,提出可能的光催化反应机理.结果表明,相比于单一g-C3N4,CoPC的负载使复合催化剂CoPC/g-C3N4的光催化降解性能提升了1.7倍,CoPC/g-C3N4的苯酚降解率达到82%.光催化性能的提升归因于CoPC的负载提升了CoPC/g-C3N4复合催化剂的光吸收性能,CoPC的负载可以有效增强光生载流子迁移速率,从而提升了光催化降解苯酚的性能.

Abstract

CoPC/g-C3N4 composite catalyst is prepared via a hydrothermal method,and its photocatalytic performance for phenol degradation is studied.The relationship between structure and properties of the catalyst is analyzed by means of FT-IR,SEM,XRD,ICP,XPS and electrochemical testing techniques,and the possible photocatalytic reaction mechanism is proposed.Experimental results show that the photocatalytic degradation performance of CoPC/g-C3N4 increases by 1.7 times than that of single g-C3N4,and the degradation rate of phenol reaches 82%over CoPC/g-C3N4.Characterization results show that the improvement of photocatalytic performance is attributed to the improvement of photo-absorption performance of CoPC/g-C3N4 under CoPC loading.The loading of CoPC can effectively enhance the migration rate of photogenerated carriers,thereby improving the catalyst's performance in photocatalytic degradation of phenol.

关键词

g-C3N4/酞菁钴/光催化/苯酚/降解

Key words

g-C3N4/cobalt phthalocyanine/photocatalysis/phenol/degradation

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基金项目

先进炭基电极材料山西省重点实验室项目(2023006)

出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCD北大核心
影响因子:0.553
ISSN:0253-4320
参考文献量7
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