现代化工2024,Vol.44Issue(12) :199-203.DOI:10.16606/j.cnki.issn0253-4320.2024.12.036

多孔电解质固体氧化物燃料电池的制备及抗积碳性能研究

Preparation of porous electrolyte solid oxides fuel cell and study on its anti-carbon deposition properties

刘志军 邱家欣 张拓 刘凤霞 许晓飞 魏炜
现代化工2024,Vol.44Issue(12) :199-203.DOI:10.16606/j.cnki.issn0253-4320.2024.12.036

多孔电解质固体氧化物燃料电池的制备及抗积碳性能研究

Preparation of porous electrolyte solid oxides fuel cell and study on its anti-carbon deposition properties

刘志军 1邱家欣 1张拓 1刘凤霞 1许晓飞 1魏炜1
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作者信息

  • 1. 大连理工大学流体与粉体工程研究设计所,辽宁 大连 116000
  • 折叠

摘要

采用共压法制备了孔隙率约为10%的具有多孔电解质的纽扣式固体氧化物燃料电池(Porous Solid Oxide Fuel Cell,P-SOFC).在700℃对P-SOFC和普通SOFC进行了电化学测试.结果表明,P-SOFC在运行中的电化学性能衰减程度以及阻抗增加程度为普通SOFC的3/5和1/5;在长时间运行8 h后还能保持0.85 V的高电位,普通SOFC的碳元素分布比P-SOFC聚集.由此可见,具有多孔的电解质结构能提高电池放电的可持续性和稳定性,该结构通过改变阳极氧碳比增加电池的抗积碳性能,使电池在甲烷氛围中长时间内保持稳定的功率输出.

Abstract

The co-pressure method is utilized to prepare a button-type porous electrolyte-containing solid oxide fuel cell(P-SOFC)with a porosity of about 10%.Electrochemical tests are conducted on P-SOFC and ordinary SOFC,respectively at 700℃.Results show that the electrochemical performance attenuation degree and impedance increase degree of P-SOFC during operation are 3/5 and 1/5 respectively that of ordinary SOFC.P-SOFC can maintain a potential as high as 0.85 V after 8 hours of long-term operation.The ordinary SOFC has more concentrated carbon element distribution than P-SOFC.It can be seen that a porous electrolyte structure can improve the sustainability and stability of battery discharge.This structure increases the anti-carbon deposition performance of the battery through changing the ratio of oxygen to carbon at anode,allowing the battery to maintain stable power output for a long time in a methane atmosphere.

关键词

多孔结构/固体氧化物燃料电池/抗积碳/电解质

Key words

porous structure/solid oxide fuel cell/resistance to carbon deposition/electrolyte

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出版年

2024
现代化工
中国化工信息中心

现代化工

CSTPCDCSCD北大核心
影响因子:0.553
ISSN:0253-4320
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