The effects of reaction temperature,volume ratio of HCl to O2 and mass space velocity on the conversion rate of HC1 were investigated by orthogonal experiment in a mixture atmosphere of 99.9％HC1+0.1％HF.The results show that under the optimum reaction conditions of 390℃,2∶1 volume ratio of HCl to O2 and 1 h-1 mass space velocity,the conversion rate of hydrogen chloride can reach 92.5％.To further verify the stability of the catalyst,the one-way conversion rate of hydrogen chloride remained stable between 91％and 93％after running for 1 500 hours.Through ICP analysis,the loss rate of the active component Cu element in the catalyst is 1.175×10-5 g/h,it is preliminarily estimated that after stable operation for 10000 hours,the loss of Cu is only 1.68％of the amount of Cu element added to the catalyst,indicating that the catalyst has good activity,stability,and fluorine resistance.
fluorinated hydrogen chloridecatalytic oxidationfluorine-resistant copper based catalystchlorine gasorthogonal experiment
NETL
NSTL
万方数据
