首页|等离子体协同催化强化氨分解制氢的研究进展

等离子体协同催化强化氨分解制氢的研究进展

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分析了不同放电形式的等离子体在氨分解领域的研究现状,着重讨论了介质阻挡放电等离子体的反应器结构参数和运行工况对氨分解效果的影响.分析了等离子体协同各类催化后对氨分解过程的影响规律和强化机制,指出通过催化剂的载体、金属活性组分等的调控优化可有效强化等离子体与催化剂的协同效应,进而提升氨分解效果并降低反应能耗.在此基础上,指出改进介质阻挡放电反应器和开发低温下高效的廉价过渡金属催化剂是基于等离子体的氨分解制氢方法的重要发展方向.
Progress on plasma-induced catalytic enhancement of ammonia decomposition for hydrogen production
This paper delves into the current situation of research on application of various plasma discharge configurations in NH3 decomposition,with a particular emphasis on the impact of reactor design parameters and operational conditions on the efficiency of ammonia decomposition under dielectric barrier discharge(DBD)plasma.Subsequently,this paper explores the synergistic effects and enhancement mechanisms between plasma and catalyst on NH3 decomposition process,confirming that the optimization of the support and active metal components of catalyst can effectively boost the synergy between plasma and catalyst,thereby enhancing the decomposition efficiency and reducing energy consumption of NH3 decomposition process.On this basis,this paper highlights two crucial directions for advancing plasma-induced NH3 decomposition to hydrogen technology,i.e.,improving dielectric barrier discharge reactor,and developing low-cost transition metal catalysts with high efficiency at low temperature.

ammonia decomposition for hydrogen productionplasmadielectric barrier dischargecatalystreaction mechanism

李钟帆、竺新波、邬晨、洪瑜

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宁波大学海运学院,浙江 宁波 315832

宁波能源集团股份有限公司,浙江 宁波 315040

宁波开发投资集团有限公司,浙江 宁波 315042

氨分解制氢 等离子体 介质阻挡放电 催化剂 反应机理

2025

现代化工
中国化工信息中心

现代化工

北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2025.45(1)