首页|NbTe2/MXene超结构钾离子电池负极的制备及其性能研究

NbTe2/MXene超结构钾离子电池负极的制备及其性能研究

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针对较大尺寸的钾离子在钾离子电池充放电过程中导致负极扩散动力学缓慢并伴随着剧烈的体积变化问题,制备了NbTe2 纳米针垂直生长在MXene纳米片上的三维超结构NbTe2/MXene.结果表明,该三维超结构具有优异的循环稳定性和倍率性能,在 0.2 A/g的电流密度下循环150 圈后,可逆比容量仍达到 306.8 mAh/g,容量保持率为 68.4%,平均每圈容量损耗率仅为 0.21%.即使在20A/g的大电流密度下仍展现出139.8 mAh/g的可逆容量.该超结构具有比表面积大、良好的电子导电性和多活性位点等诸多优势,能够提高钾离子电池的性能,为高性能负极材料的开发提供参考.
Preparation and property of NbTe2/MXene superstructure anode for potassium ion battery
The relatively large size of potassium ions can lead to slow diffusion kinetics and accompany dramatic volume changes for anodes during the charge-discharge process of potassium-ion battery.In order to solve these problems,NbTe2/MXene with three-dimensional superstructure is prepared through NbTe2 nanoneedles vertically growing on MXene nanosheets,which exhibits excellent cycling stability and rate performance.After it has been circled over 150 cycles at a current density of 0.2 A·g-1,its reversible specific capacity still reaches 306.8 mAh·g-1 with a capacity retention of 68.4%and an average capacity loss of only0.21%per cycle.Even at a high current density of 20 A·g-1,it still achieves a reversible capacity of 139.8 mAh·g-1.This superstructure possesses numerous advantages such as a large specific surface area,good electronic conductivity,and multiple active sites,which can improve the performance of potassium ion batteries and provide valuable references for the development of high-performance anode materials.

potassium ion batteryanode materialMXeneNbTe2

董臻、吴邦军、王重权、许冠南、刘争、张业龙

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五邑大学应用物理与材料学院,广东 江门 529020

澳门大学应用物理及材料工程研究院,澳门 999078

钾离子电池 负极材料 MXene NbTe2

2025

现代化工
中国化工信息中心

现代化工

北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2025.45(1)