现代化工2025,Vol.45Issue(1) :170-177.DOI:10.16606/j.cnki.issn0253-4320.2025.01.030

磁场诱导梯度水凝胶的制备及其致动性能研究

Preparation of magnetic field-induced gradient hydrogel and study on its actuation properties

张伟腾 郑奥 从怀萍
现代化工2025,Vol.45Issue(1) :170-177.DOI:10.16606/j.cnki.issn0253-4320.2025.01.030

磁场诱导梯度水凝胶的制备及其致动性能研究

Preparation of magnetic field-induced gradient hydrogel and study on its actuation properties

张伟腾 1郑奥 1从怀萍1
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作者信息

  • 1. 合肥工业大学化学与化工学院,安徽 合肥 230009
  • 折叠

摘要

采用酸刻蚀和高温热分解法合成了2D超顺磁性Fe3O4-MXene纳米片,以Fe3O4-MXene纳米片和聚N-异丙基丙烯酰胺(PNIPAM)为原料开发了一种各向异性梯度水凝胶致动器.结果表明,Fe3O4-MXene纳米片在水凝胶前溶液中垂直向下移动,产生增量含量梯度,交联固定后得到各向异性梯度的网络结构.水凝胶在厚度上形成不同尺寸的孔径,在远离磁体的一侧孔具有相对较大的尺寸,约有 50 μm,在靠近磁体附近尺寸逐渐减小到约 5 μm.Fe3O4-MXene纳米片赋予水凝胶优异光热效应,在近红外光的照射下能够实现多种可逆的形状变化和仿生软机器人的功能.

Abstract

Two-dimensional superparamagnetic Fe3O4-MXene nanosheets are synthesized via acid etching and high temperature thermal decomposition methods,and used together with N-isopropylacrylamide as raw materials to develop an anisotropic gradient hydrogel actuator.Results show that Fe3O4-MXene nanosheets move vertically down in the hydrogel precursor solution to generate incremental content gradient,which leads to an anisotropic gradient network structure after cross-linking and fixation.The hydrogels form different sizes of pores along the thickness direction.The pores on the side away from the magnet have a relatively larger size of approximately 50 μm,and the size of the pores near the magnet gradually decrease to about 5 μm.Fe3O4-MXene nanosheets endow the hydrogel with excellent photothermal effect,which can achieve a variety of reversible deformations and bionic soft robot functions under near-infrared light irradiation.

关键词

Fe3O4-Mxene磁性纳米片/N-异丙基丙烯酰胺/光聚合/梯度水凝胶/软机器人

Key words

Fe3O4-MXene magnetic nanosheets/N-isopropylacrylamide/photopolymerization/gradient hydrogel/soft robots

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出版年

2025
现代化工
中国化工信息中心

现代化工

北大核心
影响因子:0.553
ISSN:0253-4320
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