现代化工2025,Vol.45Issue(1) :190-194.DOI:10.16606/j.cnki.issn0253-4320.2025.01.033

MIL-53(Fe、Al)/PSf共混膜的制备与性能研究

Preparation and performance study of MIL-53(Fe,Al)/PSf blended membrane

张梅 李博 甘磊 尤涵博 赵维雪
现代化工2025,Vol.45Issue(1) :190-194.DOI:10.16606/j.cnki.issn0253-4320.2025.01.033

MIL-53(Fe、Al)/PSf共混膜的制备与性能研究

Preparation and performance study of MIL-53(Fe,Al)/PSf blended membrane

张梅 1李博 1甘磊 1尤涵博 1赵维雪1
扫码查看

作者信息

  • 1. 东北石油大学化学化工学院,黑龙江 大庆 163318
  • 折叠

摘要

通过溶剂热法合成了双金属有机框架MIL-53(Fe、Al)亲水性材料,与聚砜(PSf)共混并通过非溶剂致相分离法制备MIL-53(Fe、Al)/PSf共混膜.探究了MIL-53(Fe、Al)的添加质量分数对共混膜的结构和亲水性、渗透性、截留性以及抗污染性能的影响.结果表明,当MIL-53(Fe、Al)的添加质量分数为 0.3%时,与原膜相比,水接触角降低了 28.81°,达到 54.78°;纯水通量提高了10.21 倍,达到 179.15 L/(m2·h·bar).MIL-53(Fe、Al)的加入,显著提高了PSf超滤膜的亲水性和抗污染性能.

Abstract

MIL-53(Fe,Al),a bimetallic organic framework hydrophilic material,is synthesized via solvothermal method,and blended with polysulfone(PSf)to prepare MIL-53(Fe,Al)/PSf blended membrane through non-solvent induced phase separation method.Influences of the addition amount of MIL-53(Fe,Al)on the structure,hydrophilicity,permeability,retention,and anti-fouling performances of the blended membrane are explored.It is shown that the water contact angle of the blended membrane is 28.81° less than that of the original membrane,reaching 54.78° when the addition amount of MIL-53(Fe,Al)is 0.3 wt%.The pure water flux of the membrane increases by 10.21 times,reaching 179.15 L/(m2·h·bar).The addition of MIL-53(Fe,Al)significantly improves the hydrophilicity and anti-fouling performance of PSf ultrafiltration membrane.

关键词

双金属有机框架/聚砜/共混膜/亲水性/抗污染性

Key words

bimetallic organic framework/polysulfone/blended membrane/hydrophilicity/pollution resistance

引用本文复制引用

出版年

2025
现代化工
中国化工信息中心

现代化工

CSCD北大核心
影响因子:0.553
ISSN:0253-4320
段落导航相关论文