首页|可渗透反应墙耦合抽出-注入水力控制技术在石化污染场地地下水修复中的应用

可渗透反应墙耦合抽出-注入水力控制技术在石化污染场地地下水修复中的应用

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选择可渗透反应墙(PRB)耦合抽出-注入水力控制技术对地下水进行修复,利用GMS软件MODFLOW和MT3DMS模块建立假想场地的水流模型以及污染物的溶质运移模型,基于该技术修复效果的关键影响因素(地下水水动力条件、水文地质条件和修复材料污染物去除性能)设置不同情景,对比分析不同情景的模拟结果,通过数据分析拟合推导出污染物去除率r与抽出-注入量Q、含水层渗透系数K、污染物去除效率η之间的定量关系表达式,指导该技术在实际场地应用时的关键参数设置.以山东某石化污染场地为例进行对比实验,发现修复2a后耦合修复技术和单一修复技术的污染物去除率分别为75.2%~80.1%和12.9%~14.7%,表明耦合修复技术在渗透性较差、水力梯度较小的污染场地修复效果明显好于单一修复技术.
Application of permeable reaction barrier coupled pumping-recharge hydraulic control technology upon groundwater remediation in petrochemical contaminated sites
Permeable reaction barrier(PRB)coupled pumping-recharge hydraulic control technology is selected to remediate the polluted groundwater.MODFLOW and MT3DMS modules of GMS software are employed to establish the groundwater flow model and solute transport model of pollutants in a hypothetical contaminated site,while different scenarios are set according to the key influencing factors for the remediation effect of this technology,including groundwater hydrodynamic conditions,hydrogeological conditions and pollutant removal characteristics of remediation materials.Based on comparisons of various scenarios'simulation results and data analysis,the quantitative relationship expressions among pollutant removal rate r,pumping-recharge quantity Q,aquifer hydraulic conductivity K and pollutant removal efficiency η are derived,which can be used to guide the key parameter setting of the technology when applying to actual contaminated site.Taking an actual petrochemical contaminated site in Shandong province,China as an example,simulation results indicate that after 2 years of remediation,the removal rates of pollutants by the coupling remediation technology and the single PRB remediation technology are 75.2%-80.1%and 12.9%-14.7%,respectively,demonstrating that the remediation performance of the coupling remediation technology is much better than that of single PRB remediation technology in the contaminated site with poor permeability and small hydraulic gradient.

petrochemical contaminated sitesremediation of contaminated groundwaterPRB coupled pumping and recharge hydraulic control technologyremediation effectinfluencing factor

周慧娣、杨昱、徐祥健、邓圣、夏甫、韩旭、肖瀚、姜永海

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中国环境科学研究院国家环境保护地下水污染模拟与控制重点实验室,北京 100012

天津科技大学海洋与环境学院,滨海地下水利用与保护研究室,天津 300457

石化污染场地 污染地下水修复 PRB耦合抽出-注入水力控制技术 修复效果 影响因素

2025

现代化工
中国化工信息中心

现代化工

北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2025.45(1)