首页|电感耦合等离子体质谱法测定水体中7种重金属元素的方法研究

电感耦合等离子体质谱法测定水体中7种重金属元素的方法研究

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建立了电感耦合等离子体质谱法同时测定水体中铬、铜、锌、铅、镉、镍、钼7 种重金属元素含量的分析方法,在最佳的分析条件下,在一定的浓度范围内所分析的7种重金属元素具有良好的线性关系,相关系数均大于0.999 9,方法检出限为 0.03~0.11 μg/L.对水质标准物质进行测定,各元素的测定值与认定值之间无显著性误差,测定结果的相对标准偏差RSD(n=6)为0.67%~4.08%;通过对实际样品进行加标回收实验,加标回收率为 94.0%~107%;同时还对不同类型的水样进行分析,结果表明该方法具有较宽的动态线性范围,可满足各种类型水样中多种重金属元素的同时测定.
Study on determination of seven heavy metal elements in water by inductively coupled plasma mass spectrometry
A method is established for simultaneous determination of Cr,Cu,Zn,Pb,Cd,Ni,and Mo in water by inductively coupled plasma mass spectrometry.Under the optimal analysis conditions,these seven heavy metal elements analyzed show good linear relationships within a certain concentration range,with correlation coefficients greater than 0.999 9 and detection limits ranging from 0.03-0.11 μg·L-1.As this method is used to determine the water quality standard substances,there are no significant errors between the measured values and the recognized values of each element.The relative standard deviation(RSD)of the measurement results is 0.67%-4.08%(n=6).Through the spiked recovery test on the actual sample,the spiked recovery rate is 94.0%-107%.Meanwhile,this method is also used to analyze different types of water samples,indicating that this method has a wide dynamic linear range and can meet the determination of multiple heavy metal elements in various types of water samples.

inductively coupled plasma mass spectrometrywater sampleheavy metal

李小辉、袁润蕾、韩瑞、张芳、冯兰慧、王亚萍、张辰子

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河南省地质局地质灾害防治中心,自然资源部贵金属分析与勘查技术重点实验室,河南 郑州 450012

电感耦合等离子体质谱法 水体 重金属

2025

现代化工
中国化工信息中心

现代化工

北大核心
影响因子:0.553
ISSN:0253-4320
年,卷(期):2025.45(1)