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石英玻璃气孔成因与原料晶体特征的相关性

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气孔是影响石英玻璃品质的主要结构缺陷,为了探究其成因与原料石英晶体特征的关系,选择5种产自于国内外不同地区的优质脉石英为研究对象,采用偏光显微镜、ICP及XRD等仪器及方法分析不同脉石英晶体性质、包裹体特征及石英砂纯度,比较各高温熔体表观特征、原料表面与玻璃体气孔内外硅氧元素分布状态.结果显示,原生包裹体少、晶格缺陷少、结晶度高,则熔体气孔少,石英玻璃透明度高;反之,熔体气孔多,石英玻璃透明度低.石英晶体内大量微细原生包裹体是石英玻璃气孔形成的主要因素;晶格缺陷与结晶度紧密相关并可遗传,石英砂纯度与熔体气孔形成无直接关系,但晶格杂质的存在会导致晶格缺陷.
Correlation Between Formation of Pores in Quartz Glass and Crystal Characteristics of Raw Materials
Pores are the main structural defects affecting the quality of quartz glass.In order to explore the relationship between the causes and the characteristics of raw quartz crystal,5 kinds of high-quality gangue from different regions at home and abroad were selected as research objects.Polarizing microscope,ICP,XRD and other instruments and methods were used to analyze the crystal properties,inclusions and purity of different gangue sand.The apparent characteristics of high temperature melt and the distribution of silica in and out of raw material surface and vitreous pores were compared.The results show that with fewer primary inclusions,fewer lattice defects and higher crystallinity,the melt pores are less and the transparen-cy of quartz glass is higher.On the contrary,the melt has many pores and the transparency of quartz glass is low.A large number of fine primary inclusions in quartz crystals are the main factors for the formation of pores in quartz glass.Lattice defects are closely related to crystallinity and can be inherited.The purity of quartz sand is not directly related to the formation of melt pores,but the existence of lattice impurities can lead to lattice defects.

quartz glassformation of poresinclusion typelattice defects

胡修权、张立、张晋、尤大海、李国栋、张朝宏

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中南冶金地质研究所

湖北省矿物材料及应用工程技术研究中心

矿产资源综合利用宜昌市重点实验室

石英玻璃 气孔成因 包裹体类型 晶格缺陷

湖北省重点研发计划项目湖北省转制院所科技发展专项项目

2021BAA207KJFZ2019021

2024

现代矿业
中钢集团马鞍山矿山研究院有限公司

现代矿业

影响因子:0.33
ISSN:1674-6082
年,卷(期):2024.40(1)
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