现代农药2024,Vol.23Issue(3) :62-64.DOI:10.3969/j.issn.1671-5284.2024.03.011

42% 2甲·苯唑酮·莠去津可分散油悬浮剂的液相色谱分析

Analysis of MCPA-isooctyl+topramezone+atrazine 42% OD by HPLC

牛海林 武丽芬 谢欢 高梦琪 谷红玲
现代农药2024,Vol.23Issue(3) :62-64.DOI:10.3969/j.issn.1671-5284.2024.03.011

42% 2甲·苯唑酮·莠去津可分散油悬浮剂的液相色谱分析

Analysis of MCPA-isooctyl+topramezone+atrazine 42% OD by HPLC

牛海林 1武丽芬 1谢欢 1高梦琪 1谷红玲1
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作者信息

  • 1. 河北省农药检定监测总站,石家庄 050000
  • 折叠

摘要

建立了高效液相色谱法测定42% 2甲·苯唑酮·莠去津可分散油悬浮剂的方法.采用C18反相色谱柱,以甲醇+乙腈+氨水溶液(体积比44∶44∶12)为流动相,对试样中苯唑草酮、2甲4氯异辛酯和莠去津进行分离,经二极管阵列或紫外检测器检测,外标法定量.结果表明:苯唑草酮、2甲4氯异辛酯、莠去津的线性相关系数分别为0.999 72、0.999 98、0.999 95,分析方法标准偏差分别为0.019、0.153、0.071;相对标准偏差分别为0.969%、0.602%、0.470%;平均回收率分别为98.44%、100.77%、100.44%.

Abstract

A HPLC method for quantitative determination of MCPA-isooctyl+topramezone+atrazine 42%OD was established.The samples were separated by C18 reversed phase column using methanol+acetonitrile+ammonia solution(volume ratio of 44∶44∶12)as mobile phase,detected by DAD or UV detecter,and quantitated by external standard method.The results showed that the linear correlations of topramezone,MCPA-isooctyl and atrazine were 0.999 72,0.999 98 and 0.999 95,the standard deviations were 0.019,0.153 and 0.071,the relative standard deviations were 0.969%,0.602%and 0.470%,and the average recoveries were 98.44%,100.77%and 100.44%.

关键词

苯唑草酮/2甲4氯异辛酯/莠去津/高效液相色谱/分析

Key words

topramezone/MCPA-isooctyl/atrazine/HPLC/analysis

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出版年

2024
现代农药
江苏省农药协会 江苏省农药研究所股份有限公司 江苏省农药科技信息站

现代农药

CSTPCD
影响因子:0.471
ISSN:1671-5284
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