现代农药2024,Vol.23Issue(4) :50-54.DOI:10.3969/j.issn.1671-5284.2024.04.010

吡唑醚菌酯在冬枣中的残留消解及膳食风险评估

Residue degradation and dietary risk assessment of pyraclostrobin in winter jujube

陈勇达 张嘉坤 李丽梅 郑振山 钱训
现代农药2024,Vol.23Issue(4) :50-54.DOI:10.3969/j.issn.1671-5284.2024.04.010

吡唑醚菌酯在冬枣中的残留消解及膳食风险评估

Residue degradation and dietary risk assessment of pyraclostrobin in winter jujube

陈勇达 1张嘉坤 1李丽梅 1郑振山 1钱训1
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作者信息

  • 1. 河北省农林科学院生物技术与食品科学研究所,石家庄 050051
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摘要

2021-2022年在河北黄骅开展了 250 g/L吡唑醚菌酯乳油在冬枣中的规范残留田间试验,样品采用QuEChERS法净化,气相色谱-电子捕获检测器检测分析,得出吡唑醚菌酯在冬枣中的残留消解规律,并对其进行膳食风险评估.2年残留消解试验结果显示,吡唑醚菌酯在冬枣中的半衰期分别为9.86、11.8d,消解规律符合一级动力学方程;最终残留试验结果显示,末次药后14~28 d,吡唑醚菌酯残留量为0.297~0.684 mg/kg,其中,末次药后21 d的残留试验中值为0.432 mg/kg.膳食风险评估得出风险商为0.62%,膳食摄入风险可接受.建议250 g/L吡唑醚菌酯乳油在冬枣上使用剂量为3 000~4 000倍液,每季最多施药3次,施药间隔期7d,安全间隔期21 d.

Abstract

The standardized residual field trials of pyraclostrobin 250 g/L EC in winter jujube were carried out in Huanghua,in 2021-2022.The samples were extracted and purified by QuEChERS,and detected by GC-ECD.Then the residue degradation rule of pyraclostrobin in winter jujube was obtained,and the dietary risk assessment was conducted.The residue degradation tests showed that the half-lives of pyraclostrobin in winter jujube were 9.86 d,11.80 d,and the degradation dynamics accorded with the first-order reaction dynamic equations.The final residues were 0.297-0.684 mg/kg,at the 14-28 d after the last dose.The STMR of the 21 d was 0.432 mg/kg and the risk quotient was 0.62%,the dietary risk of pyraclostrobin was acceptable.It was suggested that pyraclostrobin 250 g/L EC was used in winter jujube with a dose of 3 000-4 000 times,the maximum application time was 3,the application interval was 7 d,and the pre-harvest interval was 21 d.

关键词

吡唑醚菌酯/冬枣/残留量/消解规律/安全间隔期/风险评估

Key words

pyraclostrobin/winter jujube/residue/degradation/pre-harvest interval/dietary risk assessment

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基金项目

河北省重点研发计划项目(21326803D)

出版年

2024
现代农药
江苏省农药协会 江苏省农药研究所股份有限公司 江苏省农药科技信息站

现代农药

CSTPCD
影响因子:0.471
ISSN:1671-5284
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