现代农药2024,Vol.23Issue(4) :59-63.DOI:10.3969/j.issn.1671-5284.2024.04.012

QuEChERS-超高效液相色谱-串联质谱法测定水稻中(口恶)嗪草酮残留研究

Determination of oxaziclomefone residues in rices by QuEChERS-UPLC-MS/MS

杜功名 叶剑 房兴婷 张欣欣 陈刘阳 查欣欣 王洪雷
现代农药2024,Vol.23Issue(4) :59-63.DOI:10.3969/j.issn.1671-5284.2024.04.012

QuEChERS-超高效液相色谱-串联质谱法测定水稻中(口恶)嗪草酮残留研究

Determination of oxaziclomefone residues in rices by QuEChERS-UPLC-MS/MS

杜功名 1叶剑 1房兴婷 1张欣欣 1陈刘阳 1查欣欣 1王洪雷2
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作者信息

  • 1. 江苏恒生检测有限公司,南京 210046
  • 2. 江苏省农药研究所股份有限公司,南京 210046
  • 折叠

摘要

探究了利用超高效液相色谱-串联质谱检测水稻中嗯嗪草酮残留的方法.水稻样品采用QuEChERS法处理后,经超高效液相色谱柱分离,基质匹配标准曲线外标法定量.结果表明:方法线性相关系数>0.999;在添加水平0.002~1.0 mg/kg时,噁嗪草酮的回收率为81%~95%,相对标准偏差为1.1%~9.8%,在水稻样品中的定量限为0.002 mg/kg.方法线性关系良好,操作简单,准确高效,适用于水稻样品中(口恶)嗪草酮农药残留的快速筛查和定量检测.

Abstract

A method for the determination of oxaziclomefone residues in rices was developed by UPLC-MS/MS.The analytes were purified by QuEChERS,and quantified by an external standard method.The results indicated that the correlation coefficients of the method were more than 0.999.The recoveries of oxaziclomefone were 81%-95%at the adding level of 0.002-1.0 mg/kg,the relative standard deviations ranged from 1.1%to 9.8%,and the limit of quantitation in rices was 0.002 mg/kg.The method was suitable for rapid screening and quantitative analysis of oxaziclomefone in rices with convenient,high precision and efficient.

关键词

(口恶)嗪草酮/水稻/QuEChERS/超高效液相色谱-串联质谱/残留检测

Key words

oxaziclomefone/rice/QuEChERS/UPLC-MS/MS/residue detection

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出版年

2024
现代农药
江苏省农药协会 江苏省农药研究所股份有限公司 江苏省农药科技信息站

现代农药

CSTPCD
影响因子:0.471
ISSN:1671-5284
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