现代塑料加工应用2024,Vol.36Issue(1) :43-46.DOI:10.19690/j.issn1004-3055.20230054

PGA/PBAT共混膜的结晶行为研究

Study on Crystallization Behaviors of PGA/PBAT Blend Film

王子君 陈明明 周炳 贾钦 王洪学
现代塑料加工应用2024,Vol.36Issue(1) :43-46.DOI:10.19690/j.issn1004-3055.20230054

PGA/PBAT共混膜的结晶行为研究

Study on Crystallization Behaviors of PGA/PBAT Blend Film

王子君 1陈明明 1周炳 1贾钦 1王洪学1
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作者信息

  • 1. 中石化(上海)石油化工研究院有限公司,上海,201208
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摘要

采用单螺杆挤出流延机制备了一系列聚乙醇酸/聚对苯二甲酸共己二酸丁二酯(PGA/PBAT)共混膜,采用小角 X射线散射仪(SAXS)、广角X射线散射仪(WAXS)、差示扫描量热仪(DSC)和宽频介电电阻抗谱仪等研究了PGA用量变化对PGA/PBAT共混膜中各组分结晶度与分子链运动的影响规律.结果表明:PGA/PBAT共混膜中PGA和PBAT的结晶度均受PGA用量的影响.PGA的结晶度随PGA用量增加呈现先增大后减小的趋势.当PGA质量分数为 40%时,PGA/PBAT共混膜中形成了特殊的局部有序结构,对PGA/PBAT共混物的实际应用具有指导意义.

Abstract

A series of polyglycolic acid/poly(butylene-adipate-co-terephthalate)(PGA/PBAT)blend films were prepared using a single screw extrusion casting machine.The effects of PGA content changes on the crystallinity and molecular chain motion of each component in the PGA/PBAT blend films were studied using small-angle X-ray scatterometer(SAXS),wide-angle X-ray scatterometer(WAXS),differential scanning calorimetry(DSC)and broadband dielectric impedance spectrometer.The results show that the crystallinity of PGA and PBAT in PGA/PBAT blend film is affected by the amount of PGA used.The crystallinity of PGA shows a trend of first increasing and then decreasing with the increase of PGA amount.When the mass fraction of PGA is 40%,a special local ordered structure is formed in PGA/PBAT blend film,which has guiding significance for the practical application of PGA/PBAT blends.

关键词

聚乙醇酸/聚对苯二甲酸共己二酸丁二酯/介电谱/结晶

Key words

polyglycolic acid/poly(butylene-adipate-co-terephthalate)/broadband dielectric spectroscopy/crystallization

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出版年

2024
现代塑料加工应用
中国石化扬子石油化工有限公司 中国石化集团资产经营管理有限公司扬子石化分公司

现代塑料加工应用

CSTPCD北大核心
影响因子:0.343
ISSN:1004-3055
参考文献量14
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