首页|PPR冷热水管专用树脂性能与结构分析

PPR冷热水管专用树脂性能与结构分析

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分析了 3 种不同短期静液压性能无规共聚聚丙烯(PPR)冷热水管专用树脂(分别记为 PPR-1,PPR-2,PPR-3)的相对分子质量及其分布、分子序列结构、热结晶分级、熔融温度和结晶温度等,研究了短期静液压性能与聚丙烯树脂结构组成的关联性.结果表明:3 种PPR冷热水管专用树脂的熔体流动速率、相对分子质量及其分布、乙烯含量均基本一致,但共聚单体乙烯分散度和聚丙烯链规整度均存在差异.PPR-1 的共聚单体乙烯分散度和聚丙烯链规整度均较低,且共聚单体乙烯更多分布在相对分子质量较小的分子链上,使材料局部强度较低,管材在高压下发生局部破坏的可能性较大,短期静液压性能较低.
Analysis on Property and Structure of PPR Cold and Hot Water Pipe Special Resin
The relative molecular weight and distribution,molecular sequence structure,thermal crystallization classification,melting temperature and crystallization temperature of three types of random copolymer polypropylene(PPR)special resins for cold and hot water pipes with different short term static hydraulic performance(referred to as PPR-1,PPR-2,PPR-3)were analyzed.The correlation between short term static hydraulic performance and the structural composition of polypropylene resin was studied.The results show that the melt flow rate,molecular weight and distribution and content of ethylene of the three PPR special resins for cold and hot water pipes are basically consistent,but there are differences in the dispersion of ethylene and the regularity of polypropylene chains.The ethylene dispersion and polypropylene chain regularity of PPR-1 comonomer are both low.The comonomer ethylene is more distributed on molecular chains with relatively small molecular weights,resulting in lower local strength of the material.The possibility of local damage to the pipe under high pressure is higher,and short term static hydraulic performance is lower.

random copolymer polypropylenepipehydrostatic pressure

李丽

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中国石油化工股份有限公司齐鲁分公司研究院,山东 淄博,255400

无规共聚聚丙烯 管材 静液压

2024

现代塑料加工应用
中国石化扬子石油化工有限公司 中国石化集团资产经营管理有限公司扬子石化分公司

现代塑料加工应用

CSTPCD北大核心
影响因子:0.343
ISSN:1004-3055
年,卷(期):2024.36(3)