首页|3D打印医用多孔钛合金阳极氧化修饰及其性能研究

3D打印医用多孔钛合金阳极氧化修饰及其性能研究

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目的 探讨阳极氧化对3D打印多孔Ti-6Al-4V合金中Al/V金属离子的析出的影响.方法 采用阳极氧化对3D打印多孔Ti-6Al-4V合金进行表面修饰处理,研究阳极氧化前后,多孔Ti-6Al-4V合金的显微组织结构、表面形貌以及离子析出特性.结果 阳极氧化表面修饰并未改变多孔Ti-6Al-4V合金的α+β相组成,其表面形貌也未发生改变,合金表面成分中O元素含量增加6.48%,未引入非基体元素.阳极氧化显著降低了3D打印多孔Ti-6Al-4V合金中Al/V金属离子的析出,Hank′s溶液中浸提5周的结果显示,经阳极氧化后,Al离子析出溶度降低了93.4%,V离子析出浓度降低89.5%.结论 阳极氧化通过降低Al/V离子的析出,降低潜在毒性的风险,是进一步提高3D打印多孔Ti-6Al-4V钛合金植入器械安全性的有益途径.
Study on anodic oxidation modification and properties of 3D printed porous medical titanium alloy
Objective To investigate the influence of anodic oxidation on the release of Al/V metal ions in 3D printed porous Ti-6Al-4V alloy.Methods The surface of 3D printed porous Ti-6Al-4V alloy was modified by anodic oxidation,and the microstructural organization,surface morphology,and ion release characteristics of the porous Ti-6Al-4V alloy before and after anodic oxidation were studied.Results Anodic oxidation surface modification did not change the α+β phase composition of the porous Ti-6Al-4V alloy,and its surface morphology was not changed.The O element content in the alloy surface increased by 6.48%,and no non-matrix elements were introduced.Anodic oxidation significantly reduced the release of Al/V metal ions in 3D printed porous Ti-6Al-4V alloy.The results of Hank's solution immersion for 5 weeks showed that after anodic oxidation,the solubility of Al ions was reduced by 93.4%,and the concentration of V ions was reduced by 89.5%.Conclusion Anodic oxidation,which reduces the release of Al/V ions and reduces the risk of potential toxicity,is a beneficial approach to further improve the safety of 3D printed porous Ti-6Al-4V titanium alloy implant devices.

3D printingTi-6Al-4VAnodic oxidationIon precipitation

黄朝阳、甄珍、王健、王浩、张芹、魏崇斌

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北京爱康宜诚医疗器材有限公司,北京 102200

中国医疗器械有限公司,北京 100028

中国食品药品检定研究院,北京 102629

天衍医疗器材有限公司,常州 213149

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3D打印 Ti-6Al-4V 阳极氧化 离子析出

国家骨科与运动康复临床医学研究中心创新基金重点项目

NCRC-CXJJ-ZD1-1

2024

现代仪器与医疗
中国科学器材公司

现代仪器与医疗

影响因子:1.47
ISSN:2095-5200
年,卷(期):2024.30(5)