首页|稀土对高强车轮钢夹杂物赋存特征的影响研究

稀土对高强车轮钢夹杂物赋存特征的影响研究

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结合高温模拟实验和热力学分析,探讨了稀土对高强车轮钢中夹杂物类型及尺寸分布的影响,并与传统的钙处理钢进行了对比.研究结果表明,铝脱氧车轮钢经钙处理后夹杂物主要为Al2O3、MnS、(Mn,Ca)S和CaO-Al2O3以及Al2O3-(Mn,Ca)S和CaO-Al2O3-CaS包裹型复合夹杂物;与钙处理钢对比,车轮钢经稀土处理后,钢中A12O3夹杂物数量减少,MnS和(Ca,Mn)S夹杂物消失,生成了近球形的Ce2O2S、Ce2O3夹杂,夹杂物尺寸显著减小;随稀土含量的增加[w(Ce)=0.0160%~0.0250%],不大于5 µm的夹杂物数量占比由91.0%提升至99.8%,稀土细化夹杂物效果显著.热力学分析表明:在1600℃条件下,随着车轮钢中w(Ce)由0增加至0.0300%,钢液中主要夹杂物类型的变化规律为Al2O3→CeAlO3→Ce2O3→Ce2O2S.通过稀土处理可实现钢中Al2O3夹杂物的变质,并有效抑制凝固过程中MnS夹杂的生成,生成Ce2O2S、Ce2O3夹杂.
Effect of Rare Earth on the Occurrence Characteristics of Inclusions in High-strength Wheel Steel
The effects of rare earth on the type and size distribution of inclusions in high-strength wheel steel were investi-gated by high temperature simulation experiment and thermodynamic analysis,and the occurrence characteristics of inclusions in rare earth treated steel was compared with the traditional calcium treated.The results show that the inclusions in aluminum deoxidized wheel steel after calcium treatment are mainly Al2O3,MnS,(Mn,Ca)S and CaO-Al2O3,and Al2O3-(Mn,Ca)S and CaO-Al2O3-CaS wrapped composite inclusions.Compared with calcium-treated steel,the content of A12O3 inclusions in wheel steel after rare earth treatment is reduced,MnS and(Ca,Mn)S nearly spherical inclusions of Ce2O3 and Ce2O2S were formed,and the size of inclusions decreased significantly.With the increase of rare earth content[w(Ce)=0.0160%~0.0250%],the proportion of inclusions ≤5 μm increased from 91.0%to 99.8%,and the effect of rare earth refining inclu-sions was remarkable.In addition,the thermodynamic analysis shows that,with the increase of w(Ce)in wheel steel from 0 to 0.0300%,the change rule of main inclusions in molten steel is Al2O3→CeAlO3→Ce2O3→Ce2O2S at 1600 ℃.The modifi-cation of Al2O3 inclusions in steel can be realized by rare earth treatment,and the formation of MnS inclusions during solidifi-cation can be effectively suppressed,resulting in Ce2O2S and Ce2O3 inclusions.

wheel steelrare earthinclusionthermodynamic analysissize refinement

刘军、韩荣荣、张波、李明光、苗隽、刘宏亮、刘承军

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本钢集团有限公司技术中心先进汽车用钢开发与应用技术国家地方联合工程实验室,辽宁 本溪 117000

东北大学冶金学院,辽宁 沈阳 110819

车轮钢 稀土 夹杂物 热力学分析 尺寸细化

国家自然科学基金项目国家自然科学基金项目辽宁省"兴辽英才计划"项目辽宁省优秀青年科学基金项目

52174383U1908224XLYC20020472022-YQ-09

2024

稀土
中国稀土学会 包头稀土研究院

稀土

CSTPCD北大核心
影响因子:1.172
ISSN:1004-0277
年,卷(期):2024.45(2)
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