首页|Nd-Fe-B磁体掺杂Tb-Fe-B制备高性能大块永磁体

Nd-Fe-B磁体掺杂Tb-Fe-B制备高性能大块永磁体

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应新能源大型设备器件需求,制备兼具高剩磁、高矫顽力的大块永磁材料成为当前研发重点.不同于晶界扩散技术(GBDP),采用双合金工艺(Nd-Fe-B磁体掺杂Tb19Fe75B6)制备的多主相(Nd,Tb)-Fe-B烧结磁体,不仅可实现高剩磁与高矫顽力而且体型可控,体现出更高的实用价值.微组织分析显示,掺杂Tb19Fe75B6使得磁体晶界优化并在Nd2Fe14B晶粒表层形成(Nd,Tb)2Fe14B壳层,结合Tb2Fe14B相的存在,矫顽力得以显著提升.而导致多主相(Nd,Tb)-Fe-B磁体同时实现高剩磁与高矫顽力,主要归因于微结构中Tb2Fe14B单晶与Nd2Fe14B单晶共存所触发的界面耦合效应.该研究结果为制备高性能大块永磁材料提供了一种可靠、有效的途径.
Preparation of High-performance Bulk Permanent Magnets by Doping Tb-Fe-B in Nd-Fe-B Magnets
In response to the demand for large equipment components in new energy,the preparation of large permanent magnet materials with high remanence and high coercivity has become the focus of current research and development.Unlike grain boundary diffusion technology(GBDP),the multi-main-phase(Nd,Tb)-Fe-B sintered magnet prepared by the dual-al-loy process(Nd-Fe-B magnet doped with Tb19Fe75B6)not only achieves high remanence and high coercivity but also has con-trollable shape,demonstrating higher practical value.Microstructure analysis confirmed that doping with Tb19Fe75B6 opti-mizeed the grain boundary of the magnet and formed a(Nd,Tb)2Fe14B shell layer on the surface of Nd2Fe14B grain,combined with the presence of Tb2Fe14B phase,the coercivity is significantly improved.The simultaneous realization of high remanence and high coercivity of multi-main-phase(Nd,Tb)-Fe-B magnets is mainly attributed to the interface coupling effect triggered by the coexistence of Tb2Fe14B single crystal and Nd2Fe14B single crystal in the microstructure.The results provide a reliable and effective way to prepare high-performance bulk permanent magnet materials.

(Nd,Tb)-Fe-Bmagnetic propertiesmicrostructuremagnetization reversal

邓沅、段东伟、刘威、邓潭、黄大川、李艳丽、李柱柏

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包头稀土研究院,内蒙古 包头 014030

复旦大学现代物理研究所,上海 200433

国家稀土功能材料创新中心,内蒙古 包头 014030

内蒙古科技大学材料与冶金学院,内蒙古 包头 014010

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(Nd,Tb)-Fe-B 磁性能 微组织 反磁化

2024

稀土
中国稀土学会 包头稀土研究院

稀土

CSTPCD北大核心
影响因子:1.172
ISSN:1004-0277
年,卷(期):2024.45(2)
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