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不同传热结构对固态储氢罐充/放氢性能的影响

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以LaNi5型稀土储氢合金为储氢介质,首先通过强化导热与传质的方法构建了三类传热结构,并测试了各传热结构的导热特性及其在固态储氢罐中的装填特性,重点开展固态储氢罐充/放氢研究,对比评价了三类传热结构对所装填固态储氢罐充/放氢性能的影响,并借助仿真手段对固态储氢罐充/放氢过程中的热传导行为进行了深入分析.研究结果表明,铝与石墨两类高热导材料的加入与独特的传热结构设计极大提高了装填结构的热导率,提升了固态储氢罐的充/放氢热力学与动力学水平.在三类传热结构中,RE09合金颗粒/铝屑/铝翅片复合结构(结构-Ⅱ)由于稳定的结构、高效的传热与传质效率表现出最佳的充/放氢性能.仿真结果表明,三类传热结构在充氢过程中温度沿径向向外逐渐降低,芯部为高温区,RE09合金颗粒/铝屑/铝翅片结构(结构-Ⅱ)与RE09合金粉/膨胀石墨粉复合压环结构(结构-Ⅲ)的最高温较RE09颗粒结构(结构-Ⅰ)低近400 ℃;热流分布与传热结构形式紧密相关,良好的传热结构设计使得热流不再聚集于合金中,而是流向高导热介质中,进而提升了固态储氢罐充/放氢动力学水平.
Influence of Different Heat Transfer Structures on the Hydrogen Charging/Discharging Performance of Solid State Hydrogen Storage Tanks
Three types of heat transfer structures were constructed base on a LaNi5-type rare earth-based hydrogen storage alloy as hydrogen storage medium by the method of strengthen heat conduction and mass transfer,and the heat transfer charac-teristics of each structure and their loading characteristics in solid state hydrogen storage tanks were measured.Importantly,we conducted the key research on hydrogen charging/discharging of solid state hydrogen storage tanks,then compared and evaluated the effect of three types of heat transfer structures on the hydrogen charging/discharging performance of the filled sol-id state hydrogen storage tanks,and thoroughly analyzed the heat conduction behavior of solid state hydrogen storage tanks dur-ing the hydrogen charging/discharging process using simulation methods finally.The results show that:The incorporation of a-luminum and graphite,which are high thermal conductivity materials,as well as the unique design of heat transfer structures,extremely improve the thermal conductivity and hydrogen charging/discharging thermodynamic and kinetic level of solid state hydrogen storage tanks.Among the three types of heat transfer structures,RE09 particles/Al scrap/Al fins composite structure(structure-Ⅱ)exhibits the optimum hydrogen charging/discharging performance because of its stable structure and distin-guished heat and mass transfer efficiency.Simulation results show that the temperature of three types of heat transfer structures decreasing gradually outward along the radius,which means that the core of the structures turn into the hottest zone,and the maximum temperature of RE09 particles/Al scrap/Al fins composite structure(structure-Ⅱ)and RE09 powder/expanded graphite powder compressed disks structure(structure-Ⅲ)is almost 400 ℃ lower than RE09 particles structure(structure-I).Heat flux distribution connects closely with heat transfer structure form,excellent heat transfer structure design stimu-lates the heat flux flowing to the higher thermal conductive medium rather than gathering in alloy,and elevate the hydrogen charging/discharging kinetic level of solid state hydrogen storage tanks.

heat transfer structuresolid-state hydrogen storage tankrare earth-based hydrogen storage alloyhydrogen charging/dischargingheat transfer simulation

蔚志红、王利、赵玉园、刘倩雯、胡雪娇、韩宏源、李宝犬、张旭、白金

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白云鄂博稀土资源研究与综合利用全国重点实验室,内蒙古 包头 014030

包头稀土研究院,内蒙古 包头 014030

传热结构 固态储氢罐 稀土储氢合金 充/放氢 传热仿真

2024

稀土
中国稀土学会 包头稀土研究院

稀土

CSTPCD北大核心
影响因子:1.172
ISSN:1004-0277
年,卷(期):2024.45(6)