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稀土基二维纳米材料的合成及其电催化中应用的研究进展

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电催化技术可为实现低碳经济和清洁生产提供助力,成为当今国际社会普遍关注的焦点.在实际应用过程中,多数电催化系统的效率取决于催化剂的性能.二维纳米材料具有较高的比表面积、丰富的活性位点和特殊的电子态,在电催化领域展现了巨大的应用潜力.稀土元素具有特色的4f轨道电子结构,能够有效调制催化材料活性位点状态及电子传输能力,为二维催化材料的优化提供了新思路.近年来,越来越多的稀土基二维纳米材料涌现出来并在电催化领域展现优势.本文主要论述了稀土基二维纳米材料设计理念、合成方法及其在多种电催化过程当中的应用.在此基础上,对稀土基二维纳米电催化材料当前存在的挑战进行了总结,并指明了其未来发展方向.
Research Progress in Preparation and Electrocatalytic Applications of Rare Earth-based Two-dimensional Nanomaterials
Electrocatalysis technology can help to realize low-carbon economy and clean production,thus becoming a uni-versally recognized focus of attention in the international community today.In practical applications,the efficiency of most electrocatalytic systems is determined by the performance of the catalyst.Two-dimensional nanomaterials exhibit immense ap-plication potential in electrocatalysis field due to their high specific surface area,abundant active sites and unique electronic states.Rare earth elements,with their distinctive 4f orbital electronic structure,can effectively modulate the active site state and electron transport capability of catalytic materials,providing a novel perspective for the optimization of two-dimensional catalytic materials.In recent years,an increasing number of rare earth-based two-dimensional nanomaterials have emerged and demonstrated advantages in the field of electrocatalysis.In this review,the design concept,synthesis method and application of rare earth based two-dimensional nanomaterials in various electrocatalytic processes are discussed.On this basis,the cur-rent challenges and the future development direction of rare earth-based two-dimentional nanoscale electrocatalytic materials were summarized.

rare earthtwo-dimensionalelectrocatalysissynthesis methodstructure-activity relationship

莫芃芃、王禹恒、曹婷、谭宇凡、刘宇轩、刘铮、朱瑶、刘聚哲

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华北电力大学环境科学与工程学院,北京 102206

中国环境科学研究院清洁生产与循环经济研究中心,北京 100012

中国环境科学研究院国家环境保护生态工业重点实验室,北京 100012

稀土 二维 电催化 合成方法 构效关系

2024

稀土
中国稀土学会 包头稀土研究院

稀土

CSTPCD北大核心
影响因子:1.172
ISSN:1004-0277
年,卷(期):2024.45(6)