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氢能相关稀土基低温电催化剂的研究进展

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氢能是战略性新兴产业和未来产业重点发展方向,是作为新质生产力的重要方向之一.析氢反应、析氧反应和氧还原反应是氢能制备和利用中的重要电化学过程,廉价、高效、环保和稳定的电催化剂是低成本催动以上电化学反应的关键.稀土有独特的电子结构和较低的电负性,本身可以作为电催化反应的活性位点,更重要的是,稀土元素可以作为助剂调控活性位点的电子性质,对反应物的反应能垒和吸附能等产生显著影响,进而实现改善电催化性能的目的.本文主要介绍稀土基低温电催化剂在氢能源相关电催化反应的研究进展,同时总结了以上三种反应的机理以及稀土基催化剂的合成方法.因此,本综述对于稀土元素的综合利用和稀土基电催化剂的进一步挖掘研究具有一定的指导意义.
Research Progress of Rare Earth Based Low-temperature Electrocatalysts for Hydrogen Energy
Hydrogen energy is a strategic emerging industry and the key development direction of the future industry,and is one of the important directions of China's new quality productive forces.Hydrogen evolution,oxygen evolution and oxygen reduction reactions are important electrochemical processes in the preparation and utilization of hydrogen energy,low-cost,highly efficient,environmentally friendly and stable electrocatalysts are the key to economically drive the aforesaid electro-chemical reactions.RE elements have unique electronic structures and low electronegativity,which can serve as active sites for electrocatalytic reactions,more importantly,they can act as additives to regulate the electronic properties of active sites,significantly affecting the reaction energy barrier and adsorption energy of reactants,thereby achieving the improvement of elec-trocatalytic performance.This article mainly introduces the research progress of RE-based low-temperature electrocatalysts in hydrogen energy related electrocatalytic reactions,and also summarizes the mechanisms of the above three reactions as well as the synthesis methods of RE-based catalysts.Therefore,this review has certain guiding significance for the comprehensive uti-lization of RE elements and further exploration and research of RE-based electrocatalysts.

rare earthelectrocatalysisenergy conversionhydrogen energyelectronic regulation

孙玉、张启敬、曲孔岗

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聊城大学化学化工学院山东省化学储能与新型电池技术重点实验室/协同创新中心,山东 聊城 252059

稀土 电催化 能源转换 氢能 电子调控

2024

稀土
中国稀土学会 包头稀土研究院

稀土

CSTPCD北大核心
影响因子:1.172
ISSN:1004-0277
年,卷(期):2024.45(6)