新疆钢铁2024,Issue(3) :71-73.DOI:10.20146/j.cnki.1672-4224.2024.03.025

熔融制样-X射线荧光光谱法测定炼钢萤石中主次成分

Determination of Primary and Secondary Components in Steelmak-ing Fluorite by Melting Sampling X-ray Fluorescence Spectroscopy

朱颖 史艳辉 马晓云
新疆钢铁2024,Issue(3) :71-73.DOI:10.20146/j.cnki.1672-4224.2024.03.025

熔融制样-X射线荧光光谱法测定炼钢萤石中主次成分

Determination of Primary and Secondary Components in Steelmak-ing Fluorite by Melting Sampling X-ray Fluorescence Spectroscopy

朱颖 1史艳辉 1马晓云1
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作者信息

  • 1. 新疆八一钢铁股份有限公司制造管理部,新疆 乌鲁木齐 830022
  • 折叠

摘要

使用无水四硼酸锂(Li2B4O7)、碘化铵作为熔剂,在1050℃熔融制样,以X荧光光谱法测定炼钢萤石中主次量元素,采用熔融制样和基体校正,消除了试样在测定过程中存在矿物效应.使用标样系列制作工作曲线,并对试验条件的选择、样片的制备和分析结果进行了描述.实验表明,该法简便快速,精密度好,结果准确度高.

Abstract

Anhydrous lithium tetraborate(Li2B4O7)and ammonium iodide were used as fluxes to melt and prepare samples at 1050℃.The primary and secondary elements in steel fluorite were determined by X-ray fluorescence spectroscopy.The miner-al effect in the sample during the determination process was eliminated by melting and matrix correction.The working curve was created using a series of standard samples,and the selection of experimental conditions,preparation of samples,and analy-sis results were described.The experiment shows that this method is simple,fast,precise,and has high accuracy in the results.

关键词

X射线荧光光谱法/炼钢萤石/熔融制样

Key words

X-ray fluorescence spectroscopy/steelmaking fluorite/melting sample preparation

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出版年

2024
新疆钢铁
新疆维吾尔自治区金属学会

新疆钢铁

影响因子:0.081
ISSN:1672-4224
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