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熔融制样-X射线荧光光谱法测定炼钢萤石中主次成分

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使用无水四硼酸锂(Li2B4O7)、碘化铵作为熔剂,在1050℃熔融制样,以X荧光光谱法测定炼钢萤石中主次量元素,采用熔融制样和基体校正,消除了试样在测定过程中存在矿物效应.使用标样系列制作工作曲线,并对试验条件的选择、样片的制备和分析结果进行了描述.实验表明,该法简便快速,精密度好,结果准确度高.
Determination of Primary and Secondary Components in Steelmak-ing Fluorite by Melting Sampling X-ray Fluorescence Spectroscopy
Anhydrous lithium tetraborate(Li2B4O7)and ammonium iodide were used as fluxes to melt and prepare samples at 1050℃.The primary and secondary elements in steel fluorite were determined by X-ray fluorescence spectroscopy.The miner-al effect in the sample during the determination process was eliminated by melting and matrix correction.The working curve was created using a series of standard samples,and the selection of experimental conditions,preparation of samples,and analy-sis results were described.The experiment shows that this method is simple,fast,precise,and has high accuracy in the results.

X-ray fluorescence spectroscopysteelmaking fluoritemelting sample preparation

朱颖、史艳辉、马晓云

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新疆八一钢铁股份有限公司制造管理部,新疆 乌鲁木齐 830022

X射线荧光光谱法 炼钢萤石 熔融制样

2024

新疆钢铁
新疆维吾尔自治区金属学会

新疆钢铁

影响因子:0.081
ISSN:1672-4224
年,卷(期):2024.(3)