首页|天然橡胶/改性剑麻纤维素微晶复合材料的性能研究

天然橡胶/改性剑麻纤维素微晶复合材料的性能研究

扫码查看
以剑麻纤维素为原材料提取剑麻纤维素微晶(SCF),以硬脂酸(SA)为改性剂制备硬脂酸改性剑麻纤维素微晶(SA-g-SCF),研究SA-g-SCF用量对天然橡胶(NR)/SA-g-SCF复合材料性能的影响.结果表明:随着SA-g-SCF用量的增大,NR/SA-g-SCF复合材料的Fmax-FL增大,t90呈延长趋势;与未加入SA-g-SCF的NR胶料相比,加入5份SA-g-SCF的NR/SA-g-SCF复合材料的t90基本不变,而硫化速率指数增大;随着SA-g-SCF用量的增大,NR/SA-g-SCF复合材料的邵尔A型硬度、100%定伸应力和300%定伸应力增大,拉伸强度先增大后减小;SA-g-SCF用量为5份的NR/SA-g-SCF复合材料的断面未有明显的团聚体,其拉伸强度最大(25.4 MPa),综合性能最佳.
Properties of NR/Modified Sisal Cellulose Microcrystalline Composites
Sisal cellulose microcrystalline(SCF)was extracted using sisal cellulose as raw material,stearic acid modified sisal cellulose microcrystalline(SA-g-SCF)was prepared using stearic acid(SA)as the modifier,and the effect of SA-g-SCF dosage on the properties of natural rubber(NR)/SA-g-SCF composites was studied.The results showed that,with the increase of SA-g-SCF dosage,the Fmax-FL of NR/SA-g-SCF composite increased,and the t90 showed an extended trend.Compared with NR compound without SA-g-SCF,the t90 of NR/SA-g-SCF composite with 5 phr SA-g-SCF was almost unchanged,but the vulcanization rate index increased.With the increase of SA-g-SCF dosage,the Shore A-type hardness,modulus at 100% elongation and modulus at 300% elongation of NR/SA-g-SCF composite increased and the tensile strength first increased and then decreased.NR/SA-g-SCF composite with 5 phr SA-g-SCF showed no obvious aggregates on the cross-section and had the highest tensile strength(25.4 MPa),with the best overall performance.

NRsisal cellulose microcrystallinevulcanization characteristicphysical property

黄志义、陈东明、莫静、李善荣、陆绍荣

展开 >

中国化工集团曙光橡胶工业研究设计院有限公司,广西 桂林 541000

桂林理工大学 材料科学与工程学院,广西桂林 541004

天然橡胶 剑麻纤维素微晶 硫化特性 物理性能

广西科技计划项目

桂科AB21220060

2024

橡胶工业
北京橡胶工业研究设计院

橡胶工业

CSTPCD
影响因子:0.373
ISSN:1000-890X
年,卷(期):2024.71(9)
  • 7