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流变学方法评价水包油乳液稳定性

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在 50℃下分别制备了稳定和不稳定的水包油(O/W)乳液体系,考察了 2 类乳化体系的稳态黏度曲线、流动曲线、线性黏弹性、黏弹性模量随温度变化曲线和大振幅振荡剪切(LAOS)流变性.通过三参数流变动力学新方程、Carreau-Yasuda修正方程,四参数流变动力学方程较好地拟合了相应的稳态黏度曲线、样品的流动曲线以及黏弹性模量曲线.通过主成分回归分析方法,建立了50℃下水包油乳液流变指标与稳定性的经验关系,获得了流变学评价水包油乳液稳定性的新方法,为应用流变学性质指导制备稳定乳液奠定良好基础.
Stability Evaluation for O/W Emulsions by Rheological Method
The stable and unstable O/W emulsions at 50℃were prepared respectively.The steady-shear apparent viscosities,flow curves,linear viscoelasticity,viscoelastic moduli-temperature dependence,and large amplitude oscillatory shear(LAOS)properties for these 2 kinds of O/W emulsions were investigated.A novel 3-parameter rheo-kinetics equation,a modified Carreau-Yasuda equation,and a temperature dependent 4-parameter rheo-kinetics equation had been established,fitting the corresponding steady-shear apparent viscosity,ramping shear-apparent viscosity,and the ramping temperature-viscoelastic moduli curves well.Through principal component regression analysis,the empirical relationship between the rheological index of oil in water lotion and its stability at 50℃was established,and a new rheological evaluation method for the stability of oil in water lotion was obtained.The results provide a promising basis for the preparation of stable cosmetic o/w emulsions in view of rheological properties.

O/W emulsionstabilityrheological propertyrheo-kineticsprincipal component regression analysis

周韵、付梦婕、李科晶、田珍瑞、宾钰洁、方波

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资生堂(中国)投资有限公司,上海 201203

上海市多相结构材料化学工程重点实验室/华东理工大学化工学院流变学研究室,上海 200237

水包油乳液 稳定性 流变性 流变动力学 主成分回归分析

2024

香料香精化妆品
上海香料研究所

香料香精化妆品

CSTPCD
影响因子:0.341
ISSN:1000-4475
年,卷(期):2024.(6)