西南科技大学学报2024,Vol.39Issue(3) :22-29.DOI:10.20036/j.cnki.1671-8755.2024.03.004

SPS烧结(Mg,Zn)Al2O4透明陶瓷的微观结构及性能

Microstructure and Properties of SPS Sintered(Mg,Zn)Al2O4 Transparent Ceramics

刘彪 郝艳 张文龙 王彬 张艺博
西南科技大学学报2024,Vol.39Issue(3) :22-29.DOI:10.20036/j.cnki.1671-8755.2024.03.004

SPS烧结(Mg,Zn)Al2O4透明陶瓷的微观结构及性能

Microstructure and Properties of SPS Sintered(Mg,Zn)Al2O4 Transparent Ceramics

刘彪 1郝艳 1张文龙 1王彬 1张艺博1
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作者信息

  • 1. 西南科技大学环境友好能源材料国家重点实验室 四川绵阳 621010;西南科技大学材料与化学学院 四川绵阳 621010
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摘要

尖晶石透明陶瓷是一种应用广泛的透明材料.通过放电等离子烧结技术制备了(Mg1-xZnx)Al2O4透明陶瓷,研究了 Zn2+含量对其微观结构、致密化、透光率及硬度的影响.在(Mg1-xZnx)Al2O4透明陶瓷中,随着Zn2+含量的增加,陶瓷的致密度变化并不明显,在x=0.8时致密度约为99.31%;Zn2+对陶瓷的光学透过率有显著的提升作用,在x=0.8时,陶瓷在620~6 220 nm波长范围内透过率均优于80%,且陶瓷的红外起始衰减波长发生红移;(Mg,Zn)A12O4透明陶瓷的硬度整体优于MgAl2O4,在x=0.8时,硬度达到(13.53±0.24)GPa,比MgAl2O4提高了约9%;(Mg,Zn)Al2O4透明陶瓷的断裂韧性随Zn2+离子的增加逐渐降低.Zn2+离子的加入能提高MgAl2O4尖晶石透明陶瓷透过率与硬度.

Abstract

Spinel transparent ceramics is a kind of transparent material widely used.Spark plasma sintering was used to produce the(Mg1-xZnx)A12O4 transparent ceramics,and the effects of Zn2+content on microstructure,densification,light transmission,and hardness were researched.In(Mg1-xZnx)Al2O4 transparent ceramics,the density of the material does not vary significantly with the addition of Zn2+,remaining at roughly 99.31%at x=0.8.Zn2+has a significant effect on the optical transmittance of ceramics.At x=0.8,the ceramics has rates of transmission that are greater than 80%in the 620-6 220 nm wavelength range.The beginning attenuation wavelength of the ceramic infrared is redshifted.Transparent ceramics made of(Mg,Zn)Al2O4 has a higher overall hardness than MgAl2O4.The hardness increases to(13.53±0.24)GPa at x=0.8,which is nearly 9%greater than the hardness of MgAl2O4.Transparent ceramics made of(Mg,Zn)Al2O4 gradually decrease fracture toughness as Zn2+is added.The addition of Zn2+ions can improve the transparency and hardness of MgAl2O4 spinel transparent ceramics.

关键词

(Mg1-xZnx)Al2O4透明陶瓷/放电等离子烧结技术/微观结构/光学性能/力学性能

Key words

(Mg1-xZnx)Al2O4 transparent ceramics/Spark plasma sintering/Microstructure/Optical performance/Mechanical performance

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出版年

2024
西南科技大学学报
西南科技大学

西南科技大学学报

影响因子:0.348
ISSN:1671-8755
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