热处理橡胶木中糠醛及5-甲基糠醛测定方法研究
Determination of Furfural and 5-methylfurfural in Thermally Modified Rubberwood
李彤彤 1李冠君 1李家宁 1李晓文 1李民 1秦韶山 1李雅超1
作者信息
- 1. 中国热带农业科学院橡胶研究所,国家重要热带作物工程技术研究中心橡胶分中心,海南海口,570100
- 折叠
摘要
建立高效液相色谱方法,使用C18色谱柱,以甲醇-水(75∶25,VN)为流动相,流速1.0mL/min,糠醛和5-甲基糠醛的检测波长分别为271、284 nm,保留时间分别为4.969、9.246 min,可以同时准确测定糠醛和5-甲基糠醛的含量.结果表明:测定方法具有简便易操作、灵敏度高、重复性好的优点;优化了橡胶木中糠醛和5-甲基糠醛的提取方法,用高效液相色谱法测定了橡胶木素材和不同温度(125、155、185 ℃)热处理橡胶木中糠醛和5-甲基糠醛的含量变化.随着热处理温度升高,热处理橡胶木中糠醛和5-甲基糠醛的含量由3.4 μg/g和1.9 μg/g逐渐升高至103.5 μg/g和54.1 μg/g,此结果为调控热处理橡胶木工艺提供参考.
Abstract
The established HPLC method used a C18 column with methanol-water(75∶25,V/V)as the mobile phase at a flow rate of 1.0 mL/min.The detection wavelengths of furfural and 5-methylfurfural were 271 nm and 284nm,respectively,and their retention times were 4.969 min and 9.246 min.The furfural and 5-methylfurfural can be accurately deter mined at the same time by this method.The findings indicated that the method of determination offers the advantages of being simple and easy to operate,highly sensitive,and repeat-able;the extraction method of furfural and 5-methylfurfural in rubberwood was optimized,and the contents of fur-fural and 5-methylfurfural in thermally modified rubberwood at different temperatures(125 ℃,155 ℃,185 ℃)were deter mined.It's showed that the contents of furfural and 5-methylfurfural in thermally modified rubber-wood increased from 3.4 μg/g and 1.9 μg/g to 103.5 μg/g and 54.1 μg/g.This results would provide a theoretical reference for regulating the thermally modification technology of rubberwood.
关键词
橡胶木/热处理/糠醛/5-甲基糠醛/高效液相色谱法Key words
rubberwood/thermally modification/furfural/5-methylfurfural/high performance liquid chro-matography引用本文复制引用
基金项目
海南省自然科学基金项目(322QN412)
出版年
2024
国家科技期刊平台
NSTL
万方数据